tetraphenylphosphonium tetrachlorobis(triethyl-l5-phosphaneyl)molybdate(V) | 170126-39-3

• 英文名称: tetraphenylphosphonium tetrachlorobis(triethyl-l5-phosphaneyl)molybdate(V)
• CAS: 170126-39-3
• 化学式: C₁₂H₃₀Cl₄MoP₂*C₂₄H₂₀P
• 分子量: 813.466
• InChiKey: KTOQLKSISODYLR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrachlorobis(tetrahydrofurano)molybdenum(IV) 、 四苯基溴化膦 、 三乙基膦 以 二氯甲烷 为溶剂， 以85%的产率得到tetraphenylphosphonium tetrachlorobis(triethyl-l5-phosphaneyl)molybdate(V)
  参考文献：
  名称：

  Complexes of molybdenum(III) and -(IV) with chloride and tertiary phosphine ligands; an omniumgatherum of new and old results

  摘要：

  The preparations and structures of four new mixed chloro-tertiary phosphine complexes 1,3-5 of molybdenum(III) are reported, as well as the structure of two previously known Mo-III complexes 2, 6 and the structure of an [MoCl6](2-) compound 7. These results are discussed along with data for other such compounds.

  DOI：

  10.1016/0277-5387(95)00096-b

文献信息

• Photoredox reactions of oxomolybdenum(V) with phosphines
  作者：Ralph A Isovitsch、Jerome G May、Frank R Fronczek、Andrew W Maverick

  DOI：10.1016/s0277-5387(00)00395-8

  日期：2000.6

  The fluorescent molybdenum(V)oxo complex MoOCl4(H2O)−, and oxomolybdenum(V)phosphine complexes derived from it, undergo thermal and photochemical reactions in acetonitrile with the series of phosphines PEt3, PEt2Ph, PEtPh2, and PPh3. PEt3 reacts spontaneously to form several products: crystalline (PPh4)[MoIIICl4(PEt3)2] and (PPh4)2[MoVOCl5]·2CH2Cl2; and a maroon oil that contains OPEt3, MoIVOCl2(PEt3)3

  荧光钼（V）oxo复杂MoOCl 4（H 2 O）- ，和从它派生oxomolybdenum（V）phosphine络合物，经历在乙腈与串联膦的PET的热和光化学反应3，PET 2 PH，PEtPh 2和PPh 3。PEt 3自发反应形成几种产物：晶体（PPh 4）[Mo III Cl 4（PEt 3）2 ]和（PPh 4）2 [Mo V OCl 5 ]·2CH 2 Cl 2; 栗色油，其中包含OPEt 3，Mo IV OCl 2（PEt 3）3和Mo IV Cl 4（PEt 3）2。Mo（III）和OPEt 3产物表明发生了氧原子转移。PET 2 P h和PEtPh 2示出了具有oxomolybdenum（V）在黑暗中，但照射（无显著氧化还原活性的λ > 320nm的，CH 3 CN溶液）导致还原的Mo（V）的生产和相应的膦氧化物。钼（III）产品，顺-聚体-MoCl 3（OPET 2