[ruthenium(II)(Et2O3PC5H2N(C5H4N)(C6H4)(tpy)]PF6 | 1229574-88-2

• 英文名称: [ruthenium(II)(Et2O3PC5H2N(C5H4N)(C6H4)(tpy)]PF6
• CAS: 1229574-88-2
• 化学式: C₃₅H₃₁N₅O₃PRu*F₆P
• 分子量: 846.671
• InChiKey: ZZGPBZONYGILKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 Ru(tpy)(Cl)₃ 、 diethyl 6-phenyl-2,2'-bipyridin-4-ylphosphonate 在 N-methylmorpholine 作用下， 以 甲醇 、 水 为溶剂， 以46%的产率得到[ruthenium(II)(Et2O3PC5H2N(C5H4N)(C6H4)(tpy)]PF6
  参考文献：
  名称：

  Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents

  摘要：

  Two new, potentially cyclometalating terdentate ligands bearing phosphonate substituents, Et2O3P-N boolean AND C(H)boolean AND N(5) and Et2O3P-C(H)boolean AND N boolean AND N (7), have been prepared. The corresponding ruthenium complexes, [1](+) and [2](+), respectively, were obtained by reaction with [RuCl3(tpy)]. Complexes [1](+) and [2](+) display electronic properties characteristic for cyclometalated ruthenium complexes. The platinum complex [3], of N boolean AND C(H)boolean AND N ligand 5, was also prepared and is highly phosphorescent in solution. In general, the phosphonate group electronically behaves equivalent to a carboxylate moiety. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.008