| 68494-62-2

• CAS: 68494-62-2
• 化学式: C₃₈H₃₄N₂O₂Ti
• 分子量: 598.58
• InChiKey: ZRMFYVOWRVEKPV-FQHAUYLTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 dioxide titanium
  参考文献：
  名称：

  Thermal studies and spectral characterization of the chelate of bis-(η5-cyclopentadienyl titanium(IV) with salicylidene-4-methylaniline

  摘要：

  A new chelate (eta(5) - C5H5)(2)Ti(SB)(2), where SB = O, N donor Schiff base salicylidene-4-methylaniline, was synthesized. The course of thermal degradation of the chelate was studied by thermogravimetric (TG) and differential thermal analysis (DTA) under dynamic conditions of temperature. The order of the thermal decomposition reaction and energy of activation was calculated from TG curve while from DTA curve the change in enthalpy was calculated. Evaluation of the kinetic parameters was performed by Coats-Redfern as well as Piloyan-Novikova methods which gave n = 1, Delta H = 1.114 kJ . mol(-1), Delta E = 27.01 kJ . mol(-1), Delta S = -340.12 kJ . mol(-1). K-1 and n = 1, Delta H = 1.114 kJ . mol(-1), Delta E = 20.01 kJ . mol(-1), Delta S = -342.60 kJ . mol(-1). K-1, respectively. The chelate was also characterized on the basis of different spectral studies viz. conductance, molecular weight, IR, UV-visible and H-1 NMR, which enabled to propose an octahedral structure to the chelate.

  DOI：

  10.1007/bf02547452
• 作为产物：
  描述：

  二氯二茂钛 、 2-{[(4-甲基苯基)亚氨基]甲基}苯酚 在 triethylamine 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Thermal studies and spectral characterization of the chelate of bis-(η5-cyclopentadienyl titanium(IV) with salicylidene-4-methylaniline

  摘要：

  A new chelate (eta(5) - C5H5)(2)Ti(SB)(2), where SB = O, N donor Schiff base salicylidene-4-methylaniline, was synthesized. The course of thermal degradation of the chelate was studied by thermogravimetric (TG) and differential thermal analysis (DTA) under dynamic conditions of temperature. The order of the thermal decomposition reaction and energy of activation was calculated from TG curve while from DTA curve the change in enthalpy was calculated. Evaluation of the kinetic parameters was performed by Coats-Redfern as well as Piloyan-Novikova methods which gave n = 1, Delta H = 1.114 kJ . mol(-1), Delta E = 27.01 kJ . mol(-1), Delta S = -340.12 kJ . mol(-1). K-1 and n = 1, Delta H = 1.114 kJ . mol(-1), Delta E = 20.01 kJ . mol(-1), Delta S = -342.60 kJ . mol(-1). K-1, respectively. The chelate was also characterized on the basis of different spectral studies viz. conductance, molecular weight, IR, UV-visible and H-1 NMR, which enabled to propose an octahedral structure to the chelate.

  DOI：

  10.1007/bf02547452