methyl-N,N'-bis(salicylidene)-1,2-phenylenediaminogallium | 255053-06-6

• 英文名称: methyl-N,N'-bis(salicylidene)-1,2-phenylenediaminogallium
• CAS: 255053-06-6
• 化学式: C₂₁H₁₇GaN₂O₂
• 分子量: 399.101
• InChiKey: DEWOPYNQLVHLJM-FDOBHKDXSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-二水杨醛缩-1,2-苯二胺 、 三甲基镓 以 环己烷 、 苯 为溶剂， 以82.4%的产率得到methyl-N,N'-bis(salicylidene)-1,2-phenylenediaminogallium
  参考文献：
  名称：

  Synthesis and characterisation of alkyl-N,N′-bis(salicylidene)ethylenediamino- and alkyl-N,N′-bis(salicylidene)-1,2-phenylenediaminogallium or indium complexes: crystal structure of methyl-N,N′-bis(salicylidene)-1,2-phenylenediaminoindium

  摘要：

  The reaction of trialkylgallium or indium R3M (M=In, Ga; R=Me, Et) with N,N'-ethylenebis(salicylideneimine) or 1,2-N,N'-phenylenebis(salicylideneimine) yields seven intramolecularly coordinated organogallium or organogallium complexes. Two hydroxyl protons in the ligands react with both trialkylindium and trimethylgallium, while one hydroxyl group reacts exclusively with triethylgallium. The complexes obtained have been fully characterised by elemental analysis, H-1-NMR, LR and mass spectroscopy. The structure of methyl-N,N'-bis(salicylidene)- 1,2-phenylenediaminoindium (1) has been determined by single-crystal X-ray analysis. The In atom is five coordinate in the structure. Fluorescence spectroscopy has shown that the maximum emission wavelength of 1 is 499 nm upon radiation by UV Light. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00466-0