4,4-difluoro-8-(3',5'-bis(decyloxy)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene | 1094811-95-6

• 英文名称: 4,4-difluoro-8-(3',5'-bis(decyloxy)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
• CAS: 1094811-95-6
• 化学式: C₃₉H₅₉BF₂N₂O₂
• 分子量: 636.717
• InChiKey: TVIIKUAEMUXDEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4,4-difluoro-8-(3',5'-bis(decyloxy)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene 在 碘 、 碘酸 作用下， 以 乙醇 、 水 为溶剂， 反应 1.0h， 以95%的产率得到4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  基于硼氮杂吲哚发色团的新型分子构件：在荧光金属超分子配位聚合物中的应用

  摘要：

  明亮的聚合物：描述了由通用的官能化双联吡啶（硼双联吡啶）生色团组成的荧光配位聚合物，如图所示。聚合是通过荧光发射强度的变化和峰值发射波长的变化来表示的。

  DOI：

  10.1002/chem.200802538
• 作为产物：
  描述：

  3,5-bis(decyloxy)benzaldehyde 、 2,4-二甲基吡咯 在 三氟乙酸 、 2,3-二氯-5,6-二氰基-1,4-苯醌 、 三氟化硼乙醚 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 25.0h， 以30%的产率得到4,4-difluoro-8-(3',5'-bis(decyloxy)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  基于硼氮杂吲哚发色团的新型分子构件：在荧光金属超分子配位聚合物中的应用

  摘要：

  明亮的聚合物：描述了由通用的官能化双联吡啶（硼双联吡啶）生色团组成的荧光配位聚合物，如图所示。聚合是通过荧光发射强度的变化和峰值发射波长的变化来表示的。

  DOI：

  10.1002/chem.200802538

文献信息

• Phenylethynyl-BODIPY Oligomers: Bright Dyes and Fluorescent Building Blocks
  作者：Yusuf Cakmak、Engin U. Akkaya

  DOI：10.1021/ol802446e

  日期：2009.1.1

  Boradiazaindacene dyes were converted Into phenylethynyl-BODIPY oligomers via a cycle of reactions, notably including Sonogashira couplings. As expected, as the number, n, of repeating units Increases, peak absorption and emission wavelengths are shifted to the red end of the visible spectrum, albeit with smaller increments as n Increases, Decyl groups help to keep the solubility remarkably high, and in addition to being very bright red-emitting fluorophores, their rigid rod-like structures could allow their use as functional building blocks.
• Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores
  作者：Onur Buyukcakir、O. Altan Bozdemir、Safacan Kolemen、Sundus Erbas、Engin U. Akkaya

  DOI：10.1021/ol9019056

  日期：2009.10.15

  1,3,5,7-Tetramethyl-Bodipy derivatives undergo Knoevenagel-type condensations with aromatic aldehydes to ultimately yield tetrastyryl-Bodipy derivatives. The resulting dyes absorb and emit strongly in the near IR. As the versatility of the Bodipy dyes are fully appreciated, these new tetrastyryl dyes are likely to be featured in a variety of functional supramolecular systems.
• Solid-State Dye-Sensitized Solar Cells Using Red and Near-IR Absorbing Bodipy Sensitizers
  作者：Safacan Kolemen、Yusuf Cakmak、Sule Erten-Ela、Yigit Altay、Johannes Brendel、Mukundan Thelakkat、Engin U. Akkaya

  DOI：10.1021/ol1014762

  日期：2010.9.3

  Boron-dipyrrin dyes, through rational design, yield promising new materials. With strong electron-donor functionalities and anchoring groups for attachment to nanocrystalline TiO2, these dyes proved useful as sensitizers in dye-sensitized solar cells. Their applicability in a solid-state electrolyte regime offers additional opportunities for practical applications.