3,7-bis(4-(1,4-dioxa-7,13-dithia-10-azacyclopentadecan-10-yl)styryl)-10-(4-(tert-butyl)phenyl)-2,8-diethyl-5,5-difluoro-1,9-dimethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium | 1240512-22-4

• 英文名称: 3,7-bis(4-(1,4-dioxa-7,13-dithia-10-azacyclopentadecan-10-yl)styryl)-10-(4-(tert-butyl)phenyl)-2,8-diethyl-5,5-difluoro-1,9-dimethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
• CAS: 1240512-22-4
• 化学式: C₆₁H₈₁BF₂N₄O₄S₄
• 分子量: 1111.41
• InChiKey: MLICDHDIYKYHFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  3,7-bis(4-(1,4-dioxa-7,13-dithia-10-azacyclopentadecan-10-yl)styryl)-10-(4-(tert-butyl)phenyl)-2,8-diethyl-5,5-difluoro-1,9-dimethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium 在 mercury(II) perchlorate 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  A near IR di-styryl BODIPY-based ratiometric fluorescent chemosensor for Hg(II)

  摘要：

  A novel BODIPY-based near-IR emitting probe as a selective and sensitive fluorophore for Hg(II) is synthesized. This versatile BODIPY fluorophore is functionalized for long wavelength emission at the 3 and 5 positions via a condensation reaction in which two dithiodioxomonoaza-based crown-containing phenyl units are conjugated to the BODIPY core as a chelating unit. This designed fluorophore, employing an ICT sensor can be used effectively to detect Hg(II) cations by way of a hypsochromic shift (similar to 90 nm) in both the absorption and emission spectra. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.12.025
• 作为产物：
  描述：

  4-(1,4-dioxa-7,13-dithia-10-azacyclopentadecan-10-yl)benzaldehyde 、 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-(4-tert-butylphenyl)-4-bora-3a,4a-diaza-s-indacene 在 哌啶 、 溶剂黄146 作用下， 以 苯 为溶剂， 反应 24.0h， 以20%的产率得到3,7-bis(4-(1,4-dioxa-7,13-dithia-10-azacyclopentadecan-10-yl)styryl)-10-(4-(tert-butyl)phenyl)-2,8-diethyl-5,5-difluoro-1,9-dimethyl-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
  参考文献：
  名称：

  A near IR di-styryl BODIPY-based ratiometric fluorescent chemosensor for Hg(II)

  摘要：

  A novel BODIPY-based near-IR emitting probe as a selective and sensitive fluorophore for Hg(II) is synthesized. This versatile BODIPY fluorophore is functionalized for long wavelength emission at the 3 and 5 positions via a condensation reaction in which two dithiodioxomonoaza-based crown-containing phenyl units are conjugated to the BODIPY core as a chelating unit. This designed fluorophore, employing an ICT sensor can be used effectively to detect Hg(II) cations by way of a hypsochromic shift (similar to 90 nm) in both the absorption and emission spectra. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.12.025