[Ru2(CO)2(η-C5H5)(μ-CNCH2Ph)(μ-C(CN)N(Me)CH2Ph)] | 162232-07-7

• 英文名称: [Ru2(CO)2(η-C5H5)(μ-CNCH2Ph)(μ-C(CN)N(Me)CH2Ph)]
• CAS: 162232-07-7
• 化学式: C₃₀H₂₇N₃O₂Ru₂
• 分子量: 663.703
• InChiKey: XBMOYUFUNFAMFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru2(CO)2(η-C5H5)(μ-CNCH2Ph)(μ-C(CN)N(Me)CH2Ph)] 、 三氟甲烷磺酸甲酯 以 二氯甲烷 为溶剂， 以53%的产率得到[Ru2(CO)2(η-C5H5)(μ-CN(Me)CH2Ph)(μ-C(CN)N(Me)CH2Ph)]SO3CF3
  参考文献：
  名称：

  Synthesis of dinuclear iron and ruthenium aminoalkylidene complexes and the molecular structure of the novel cis-[Ru2(CO)2(Cp)2{μ-C(CN)N(Me)Bz}2](Cp = η-C5H5; Bz CH2Ph)

  摘要：

  Repeated stepwise addition of CH3SO3CF3 and Bu(4)NCN to the diisocyanide complex [Ru-2(CO)(2)(Cp)(2)(CNBz)(2)] (Cp = eta-C5H5; Bz = CH(2)Ph) has led to the formation of the new bis-mu-aminoalkylidene complex [Ru-2(CO)(2)(Cp)(2){mu-C(CN)N(Me)Bz}(2)], which has been characterized by X-ray diffraction. The crystal contains a racemic mixture of the isomer with the same chirality at the amine nitrogens. The molecule conforms to a C-2 idealized symmetry. Selected bond distances are Ru-Ru 2.662(1), Ru-(mu-C) 2.088 (av), mu-C-N(amine) 1.479 (av) Angstrom. All the intermediate species: [Ru-2(CO)(2)(Cp)(2)(mu-CNBz){mu-CN(Me)Bz}SO3CF3, [Ru-2(CO)(2)(Cp)(2)(mu-CNBz){mu-C(CN)N(Me)Bz}] and [Ru-2(CO)(2)(Cp)(2){mu-CN(Me)Bz}{mu-C(CN)-N(Me)Bz}]SO3CF3 have been isolated and characterized spectroscopically. Attempts to extend the synthetic method to the iron diisocyanide [Fe-2(CO)(2)(Cp)(2)(CNBz)(2)] led to [Fe-2(CO)(CNBz)(Cp)(2)(mu-CO{mu-CN(Me)Bz}]SO3CF3 and [Fe-2(CO)(CNBz)-(Cp)(2)(mu-CO){mu-C(CN)N(Me)Bz}] but not to the bis(aminoalkylidene) derivative.

  DOI：

  10.1016/0022-328x(94)00012-2
• 作为产物：
  描述：

  [Ru2(CO)2(η-C5H5)(μ-CNCH2Ph)(μ-CN(Me)CH2Ph)]SO3CF3 、 氰化四丁基铵 以 二氯甲烷 为溶剂， 以50%的产率得到[Ru2(CO)2(η-C5H5)(μ-CNCH2Ph)(μ-C(CN)N(Me)CH2Ph)]
  参考文献：
  名称：

  Synthesis of dinuclear iron and ruthenium aminoalkylidene complexes and the molecular structure of the novel cis-[Ru2(CO)2(Cp)2{μ-C(CN)N(Me)Bz}2](Cp = η-C5H5; Bz CH2Ph)

  摘要：

  Repeated stepwise addition of CH3SO3CF3 and Bu(4)NCN to the diisocyanide complex [Ru-2(CO)(2)(Cp)(2)(CNBz)(2)] (Cp = eta-C5H5; Bz = CH(2)Ph) has led to the formation of the new bis-mu-aminoalkylidene complex [Ru-2(CO)(2)(Cp)(2){mu-C(CN)N(Me)Bz}(2)], which has been characterized by X-ray diffraction. The crystal contains a racemic mixture of the isomer with the same chirality at the amine nitrogens. The molecule conforms to a C-2 idealized symmetry. Selected bond distances are Ru-Ru 2.662(1), Ru-(mu-C) 2.088 (av), mu-C-N(amine) 1.479 (av) Angstrom. All the intermediate species: [Ru-2(CO)(2)(Cp)(2)(mu-CNBz){mu-CN(Me)Bz}SO3CF3, [Ru-2(CO)(2)(Cp)(2)(mu-CNBz){mu-C(CN)N(Me)Bz}] and [Ru-2(CO)(2)(Cp)(2){mu-CN(Me)Bz}{mu-C(CN)-N(Me)Bz}]SO3CF3 have been isolated and characterized spectroscopically. Attempts to extend the synthetic method to the iron diisocyanide [Fe-2(CO)(2)(Cp)(2)(CNBz)(2)] led to [Fe-2(CO)(CNBz)(Cp)(2)(mu-CO{mu-CN(Me)Bz}]SO3CF3 and [Fe-2(CO)(CNBz)-(Cp)(2)(mu-CO){mu-C(CN)N(Me)Bz}] but not to the bis(aminoalkylidene) derivative.

  DOI：

  10.1016/0022-328x(94)00012-2