[NH4][(2-[(CH3)2NCH2]C6H4-)nBuSnF3] | 1061582-76-0

• 英文名称: [NH4][(2-[(CH3)2NCH2]C6H4-)nBuSnF3]
• CAS: 1061582-76-0
• 化学式: C₁₃H₂₁F₃NSn*H₄N
• 分子量: 385.06
• InChiKey: CSICCPNVRLUGKZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [NH4][(2-[(CH3)2NCH2]C6H4-)nBuSnF3] 、 praseodymium(III) trifluoromethanesulfonate 以 四氢呋喃 为溶剂， 以52%的产率得到[(2-[(CH3)2NCH2]C6H4-)nBuSnF(μ-F)2Sn(2-[(CH3)2NCH2]C6H4-)nBuF]*2HOTf
  参考文献：
  名称：

  The differences in solid state structures of C,N-chelated nbutyltin(IV) fluorides

  摘要：

  The solid state structures of products of. uorination of LCNnBuSnCl2 ( where LCN is 2-[( CH3) 2NCH2] C6H4 -) by different methods are reported. The reaction of 3 equiv. of [ NH4]+[ LCNnBuSnF3] and Pr( OTf) 3 led to dimeric arrangement [ LCNnBuSnF( l- F) 2SnLCNnBuF] 2HOTf. Two different polymorphs of polymeric [ LCNnBuSnF2] n have been obtained by crystallization. Prepared compounds were studied by X- ray crystallographic methods, DSC and theoretical calculations at the B3LYP/ LANL2DZ level. (c) 2008 Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2008.06.010