(para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine | 247234-61-3

• 英文名称: (para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine
• CAS: 247234-61-3
• 化学式: C₃₂H₃₀CoO₃P
• 分子量: 552.555
• InChiKey: XHLJJZGSSNTQSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 对叔丁基氯苄 、 三苯基膦 在 Na-amalgam 作用下， 以 乙醚 为溶剂， 以74%的产率得到(para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine
  参考文献：
  名称：

  Preparation and molecular structures of benzyl- and phenylacetylcobalt carbonyls

  摘要：

  The benzyl-type cobalt carbonyl complexes (para-(BuC6H4CH2)-Bu-t)Co(CO)(3)PPh3 (4) and [para-ClC6H4CH2C(O)]Co(CO)(3)PPh3 (5) were prepared and characterized by analyses, spectra and X-ray single-crystal diffraction. The overall structures both of the alkylcobalt-type 4 and the acylcobalt-type 5 display trigonal bipyramidal geometry, with the two noncarbonyl ligands in the two axial positions. The relevance of the stereochemistry of complexes 4 and 5 to the supposed mechanism of the CO insertion/deinsertion on cobalt is discussed. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00157-6