| 259530-27-3

• CAS: 259530-27-3
• 化学式: C₄₂H₂₈Cl₂N₂Pd₂
• 分子量: 844.444
• InChiKey: SAFFUNZQCYQFJQ-KGJMRUDZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三苯基膦 以 丙酮 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Cyclometallation of anthracen-9-ylmethylene-phenyl-amine by palladium(II) compounds

  摘要：

  The cyclometallation of anthracen-9-ylmethylene-phenyl-amine with palladium(II) acetate and with the system PdCl2, NaCl and NaOAc . 3H(2)O is studied. In both cases, the Cl-H bond activation of the anthracen-9-yl group takes place, affording an entry to a new type of endocyclic six-membered cyclopalladated organic imine that contains a metallated aromatic carbon atom. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00567-7
• 作为产物：
  描述：

  、 lithium chloride 以 丙酮 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  Cyclometallation of anthracen-9-ylmethylene-phenyl-amine by palladium(II) compounds

  摘要：

  The cyclometallation of anthracen-9-ylmethylene-phenyl-amine with palladium(II) acetate and with the system PdCl2, NaCl and NaOAc . 3H(2)O is studied. In both cases, the Cl-H bond activation of the anthracen-9-yl group takes place, affording an entry to a new type of endocyclic six-membered cyclopalladated organic imine that contains a metallated aromatic carbon atom. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00567-7