[(3,5-bis(phenyl)-2-(2′-pyridyl)pyrrole)AuCl2] | 917500-00-6

• 英文名称: [(3,5-bis(phenyl)-2-(2′-pyridyl)pyrrole)AuCl2]
• 英文别名: [(3,5-bis(phenyl)-2-(2′-pyridyl)pyrrole)AuCl₂]；[(pyrpy)AuCl₂]
• CAS: 917500-00-6
• 化学式: C₂₁H₁₅AuCl₂N₂
• 分子量: 563.236
• InChiKey: ZQQOSWYZWXWQIU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(3,5-bis(phenyl)-2-(2′-pyridyl)pyrrole)AuCl2] 、 四甲基锡 以 四氢呋喃 、 盐酸 为溶剂， 以49%的产率得到(C₅H₄NC₄HN(C₆H₅)2)Au(CH₃)2
  参考文献：
  名称：

  A robust dimethylgold(III) complex stabilized by a 2-pyridyl-2-pyrrolide ligand

  摘要：

  Reaction of isopropyl[(2-pyridyl)alkyl]amines such as N-isopropyl-N-2-methylpyridine or N-isopropyl-N-2-ethylpyridine with aqueous solutions of NaAuCl4 led to the formation of [LAUCl(2)][AuCl4] in low yields, where L = pyridyl amine bound to gold in a bidentate fashion. Reaction of 2-(3,5-diphenyl-1H-pyrrol-2-yl)pyridine with aqueous NaAuCl4, however, proceeded with formal loss of HCl and direct formation of the gold(III) amido complex L'AuCl2, where L' = deprotonated pyrrolyl ligand. Optimization of the reaction conditions to make the new amido complex identified MeCN:H2O (1:2) as the best choice of solvent, affording product in 92% yield. This dichloro amido complex is a convenient precursor to 'AuMe2, which was found to be air-stable and thermally robust. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.083
• 作为产物：
  描述：

  sodium tetrachloroaurate(III) dihyrate 、 3,5-diphenyl-2-(2-pyridyl)pyrrole 以 水 、 乙腈 为溶剂， 以92%的产率得到[(3,5-bis(phenyl)-2-(2′-pyridyl)pyrrole)AuCl2]
  参考文献：
  名称：

  A robust dimethylgold(III) complex stabilized by a 2-pyridyl-2-pyrrolide ligand

  摘要：

  Reaction of isopropyl[(2-pyridyl)alkyl]amines such as N-isopropyl-N-2-methylpyridine or N-isopropyl-N-2-ethylpyridine with aqueous solutions of NaAuCl4 led to the formation of [LAUCl(2)][AuCl4] in low yields, where L = pyridyl amine bound to gold in a bidentate fashion. Reaction of 2-(3,5-diphenyl-1H-pyrrol-2-yl)pyridine with aqueous NaAuCl4, however, proceeded with formal loss of HCl and direct formation of the gold(III) amido complex L'AuCl2, where L' = deprotonated pyrrolyl ligand. Optimization of the reaction conditions to make the new amido complex identified MeCN:H2O (1:2) as the best choice of solvent, affording product in 92% yield. This dichloro amido complex is a convenient precursor to 'AuMe2, which was found to be air-stable and thermally robust. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.083

文献信息

• Monocyclometalated Gold(III) Complexes Bearing π-Accepting Cyanide Ligands: Syntheses, Structural, Photophysical, and Electrochemical Investigations
  作者：Alexander Szentkuti、Jai Anand Garg、Olivier Blacque、Koushik Venkatesan

  DOI：10.1021/acs.inorgchem.5b01762

  日期：2015.11.16

  electrochemical investigations of a series of gold(III) monocyclometalated complexes bearing ancillary ligands with π-accepting properties is reported. Complexes of the type [(C∧N)Au(C≡N)2] [C∧N = 2-phenylpyridine (ppy) (1), 2-(p-tolyl)pyridine (tpy) (2), 2-(2-thienyl)-pyridine (thpy) (3), 2-(5-methyl-2-thienyl)pyridine (5m-thpy) (4), 1-phenylisoquinoline (piq) (5)], and [(N∧N)Au(C≡N)2] [N∧N = 3,5-bis(p

  报道了一系列具有π-接受性质的辅助配体的金（III）单环金属化金（III）系列的合成，结构，光物理和电化学研究。该类型的复合物[（C ∧ N）的Au（C≡N）2 ] [C ∧ N = 2-苯基吡啶（PPY）（1），2-（p -甲苯基）吡啶（TPY）（2），2- （2-噻吩基）吡啶（thpy）（3），2-（5-甲基-2-噻吩基）吡啶（5m-thpy）（4），1-苯基异喹啉（piq）（5）]和[[N ∧N）Au（C≡N）2] [N ∧ N = 3,5-双（苯基）-2-（2'-吡啶基）吡咯（pyrpy）（6）]制备，并且两个氰化物作为辅助配体的影响，以及不同所述环金属化配体（电子性质1 - 5）和螯合二齿（6上的三重态发光特性）进行了研究。通过多种物理方法评估其理化性质，并通过X射线衍射研究进一步确定所选配合物的结构。1至5号综合大楼在溶液，纯净的固体，旋涂的PMMA膜中以及在2-MeTHF中在77