| 403507-98-2

• CAS: 403507-98-2
• 化学式: C₁₉H₂₂Cl₃NOTi
• 分子量: 434.629
• InChiKey: ZDUSBBFDCJXKQL-ITFXXQIYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(salicylidene)-2,6-diisopropylaniline trimethylsilyl ether 、 四氯化钛 以 正己烷 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  SYNTHESIS, REACTIONS, AND SPECTRAL [NMR (¹H, ¹³C, ²⁹Si), IR] STUDIES OF TRIMETHYLSILYL-SUBSTITUTED N-ARYLSALICYLALDIMINATES

  摘要：

  Trimethylsilyl-substituted N-arylsalicylaidiminates Me3Si (OC6H4CH=NAr) [Ar=C6H5 (1), C6H3Me2-2,6 (2), C6H2Me3-2,4,6 (3), C3H3Et2-2,6 (4), and C6H3(Pr-i)(2)-2,6 (5)] have been prepared by the equimolar reactions of Me3SiCl with N-arylsalicylaldimines (LH) in benzene using Et3N as a base. Reactions in the desired molar ratios (1:1 or 2:1) of Me3Si(OC6H4CH=NAr) with TiCl4 and ZrCl4 afford a convenient and clean synthetic procedure for the preparation of chloride-salicylaldiminate derivatives of early transition metals. Characterisations of all these new derivatives have been carried out by elemental analyses, molecular weight determinations and spectroscopic [IR, NMR (H-1, C-13 and Si-29)] studies.

  DOI：

  10.1081/sim-100107714