trans-[(η¹-CH₂C₄H₃S)PdCl(triphenylphosphine)₂] | 1392235-41-4

• 英文名称: trans-[(η¹-CH₂C₄H₃S)PdCl(triphenylphosphine)₂]
• 英文别名: trans-[(η¹-CH₂C₄H₃S)PdCl(PPh₃)₂]
• CAS: 1392235-41-4
• 化学式: C₄₁H₃₅ClP₂PdS
• 分子量: 763.615
• InChiKey: JNZDVAOICVNFEW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[(η¹-CH₂C₄H₃S)PdCl(triphenylphosphine)₂] 、 silver tetrafluoroborate 以 甲苯 为溶剂， 生成 [(η³-CH₂C₄H₃S)Pd(PPh₃)₂](tetrafluoroborate)
  参考文献：
  名称：

  η³-Furfuryl and η³-Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

  摘要：

  A number of cationic and neutral eta(3)-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous eta(3)-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.

  DOI：

  10.1021/om300568z
• 作为产物：
  描述：

  2-氯甲基噻吩 、 四(三苯基膦)钯 以 苯 为溶剂， 生成 trans-[(η¹-CH₂C₄H₃S)PdCl(triphenylphosphine)₂] 、 2-噻吩基甲基三苯基鏻氯化物
  参考文献：
  名称：

  η³-Furfuryl and η³-Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

  摘要：

  A number of cationic and neutral eta(3)-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous eta(3)-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.

  DOI：

  10.1021/om300568z