The preparation and X-ray crystal structure of [-2)}2]
作者:Rosa-Maria Catala、Diana Cruz-Garritz、Pilar Terreros、Hugo Torrens、Adrian Hills、David L. Hughes、Raymond L. Richards
DOI:10.1016/0022-328x(87)80262-0
日期:1987.7
The complex [Ru(SC6F5)2(PPh3)2] has been prepared from [RuCl2(PPh3)3] and [Pb(SC6F5)2] and shown by X-rays to have a pseudo-octahedral structure apparently with two RuHC interactions. It reacts with CO to give [Ru(SC6F5)2-(CO)2(PPh3)2].
复合物[Ru(SC 6 F 5)2(PPh 3)2 ]是由[RuCl 2(PPh 3)3 ]和[Pb(SC 6 F 5)2 ]制备的,并通过X射线显示具有伪八面体结构显然具有两个RuHC相互作用。它与CO反应生成[Ru(SC 6 F 5)2-(CO)2(PPh 3)2 ]。
Jessop, Philip G.; Rettig, Steven J.; Lee, Chung-Li, Inorganic Chemistry, 1991, vol. 30, # 24, p. 4617 - 4627
作者:Jessop, Philip G.、Rettig, Steven J.、Lee, Chung-Li、James, Brian R.