[(η(5)-1,3-tBu2C5H3)Rh(μ-Cl)2]2[C2(B10H10)] | 1070885-97-0

• 英文名称: [(η(5)-1,3-tBu2C5H3)Rh(μ-Cl)2]2[C2(B10H10)]
• CAS: 1070885-97-0
• 化学式: C₂₈H₅₂B₁₀Cl₂Rh₂
• 分子量: 773.548
• InChiKey: JQGBKKJOZFBDHJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  正丁基锂 、 1,2-dicarba-closo-dodecaborane(12) 、 [RhCp_tCl₂]₂ 以 四氢呋喃 、 乙醚 为溶剂， 以70%的产率得到[(η(5)-1,3-tBu2C5H3)Rh(μ-Cl)2]2[C2(B10H10)]
  参考文献：
  名称：

  Half-sandwich binuclear carbaborane compounds: Closo-carbaboranes as good σ-donar ligands

  摘要：

  The synthesis of half-sandwich binuclear transition-metal complexes containing the Cab(C,C) chelate ligands (Cab(C,C) = C2B10H10 (1)) is described. 1Li(2) was reacted with chloride-bridged dimers [ Cp*RhCl-(mu- Cl)](2) (Cp* = eta(5)-C-5(CH3)(5)), [Cp'RhCl(mu-Cl)](2) (Cp' = eta(5)-1,3-tBu(2)C(5)H(3)), [Cp*IrCl(mu-Cl)](2) and [(p-cymene)-RuCl( mu-Cl)](2) to give half-sandwich binuclear complexes [ Cp*Rh(mu-Cl)](2)(Cab(C,C)) ( 2), [Cp'Rh(mu-Cl)](2)(Cab(C,C)) [3),[ Cp*Ir(mu-Cl)](2)(Cab(C,C)) ( 4) and [(p-cymene) Ru(mu-Cl)](2)(Cab(C,C)) ( 5), respectively. Addition reactions of the ruthenium complex 5 with air gave [( p-cymene)(2)Ru-2(mu-OH)(mu-Cl)](Cab(C,C)) ( 6), rhodium complex 2 with LiSPh gave [Cp*Rh(mu-SPh)](2)(Cab(C,C)) ( 7). The complexes were characterized by IR, NMR spectroscopy and elemental analysis. In addition, X-ray structure analysis were performed on complexes 2-7 where the potential C,C-chelate ligand was found to coordinate in a bidentate mode as a bridge. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.06.030