[(Me2C)(Me2Si)(η5-C5H3)2Mo2(CO)4(μ-η2:η2-CS3)] | 1017584-70-1

• 英文名称: [(Me2C)(Me2Si)(η5-C5H3)2Mo2(CO)4(μ-η2:η2-CS3)]
• CAS: 1017584-70-1；1017536-09-2
• 化学式: C₂₀H₁₈Mo₂O₄S₃Si
• 分子量: 638.524
• InChiKey: MUWZVSPILQIBCD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二硫化碳 、 [(η**(5)-C5H3)2(CMe2)(SiMe2)]Mo2(CO)6 以 甲苯 为溶剂， 以9%的产率得到[(Me2C)(Me2Si)(η5-C5H3)2Mo2(CO)4(μ-η1:η2-CS)]
  参考文献：
  名称：

  Unexpected reactions of (Me2C)(Me2Si)[(η5-C5H3)Mo(CO)3]2 with diazoalkane and carbon disulfide: Activation and cleavage of the NN bond and disproportionation of carbon disulfide

  摘要：

  The N-N bond cleavage of diazoalkane Ar2CN2 following a orthometalation of the aryl occurred in the thermal reactions with (Me2C)(Me2Si)[(eta(5)-C5H3)Mo(CO)(3)](2) (1), which led to (Me2C)( Me2Si)[(eta 5-C5H3)Mo-2(CO)(2)(O){mu- eta(1):eta(2)-N = C(RC6H3)(RC6H4)}] [R = H (2), p-Me ( 3)]. Two products (Me2C)(Me2Si)[(eta(5)-C5H3)(2)Mo-2(CO)(4)(mu-eta(1):eta(2)-CS)] (4) and (Me2C)(Me2Si)[(eta(5)-C5H3)(2)Mo-2 (CO)(4)(mu-eta(2):eta(2)-CS3)] (5) were isolated in the reaction of complex 1 with CS2 with the disproportionation of carbon disulfide. The molecular structures of 2-5 have been determined by X-ray diffraction analysis. The proposed mechanism was discussed. (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.11.048