[Cu(2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline)(PPh3)2]BF4 | 1239970-32-1

• 英文名称: [Cu(2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline)(PPh3)2]BF4
• CAS: 1239970-32-1
• 化学式: BF₄*C₅₅H₄₂CuN₄P₂
• 分子量: 971.263
• InChiKey: WPWWAUOENCAIHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline)(PPh3)2]BF4 、 5-(5-bromopent-1-yl)bicyclo[2.2.1]hept-2-ene 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 20.0h， 以60%的产率得到
  参考文献：
  名称：

  Copper-containing copolymers based on the norbornene monomers. Synthesis, photo-, and electroluminescent properties

  摘要：

  New copper(I) complexes containing the norbornene-substituted phenanthroline ligand were synthesized. Based on these compounds, new carbon-chain copper-containing copolymers possessing the photo- and electroluminescent properties were obtained by the metathesis polymerization.

  DOI：

  10.1134/s107036321301012x
• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 三苯基膦 、 2-phenyl-1H-imidazo[4,5-f ][1,10]phenanthroline 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 [Cu(2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline)(PPh3)2]BF4
  参考文献：
  名称：

  Copper-containing copolymers based on the norbornene monomers. Synthesis, photo-, and electroluminescent properties

  摘要：

  New copper(I) complexes containing the norbornene-substituted phenanthroline ligand were synthesized. Based on these compounds, new carbon-chain copper-containing copolymers possessing the photo- and electroluminescent properties were obtained by the metathesis polymerization.

  DOI：

  10.1134/s107036321301012x