[(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(2,2'-bipyridine)ruthenium(II)] tetrafluoroborate | 529499-21-6

• 英文名称: [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(2,2'-bipyridine)ruthenium(II)] tetrafluoroborate
• CAS: 529499-21-6
• 化学式: BF₄*C₃₈H₃₈N₂PRu
• 分子量: 741.581
• InChiKey: VQGBOAFVYZQTCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氟硼酸铵 、 五甲基环戊二烯基双(三苯基膦)氯化钌(II) 、 乙腈 以 甲苯 为溶剂， 以57%的产率得到[(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(2,2'-bipyridine)ruthenium(II)] tetrafluoroborate
  参考文献：
  名称：

  Synthesis and characterization of [(Cp*)Ru(PPh3)(N-base)]X and [(η5-C9H7)Ru(PPh3)(N-base)]X complexes: crystal and molecular structure of the complex [(η5-C9H7)Ru(PPh3)(phen)]PF6

  摘要：

  The reactions of [(eta(5)-Cp*)Ru(PPh3)(2)(CH3CN)]X (1) and [(eta(5)-indenyl)Ru(PPh3)(2)(CH3CN)]X (2) (eta(5)-CP* = eta(5)-C5Me5; eta(5)-indenyl = eta(5) -C9H7; X = BF4 or PF6) with 2,2'-bipyridine (bipy.) and 1,10-phenanthroline (phen.) in benzene or toluene yielded complexes of the type [(eta(5)-Cp*)Ru(PPh3)(L-2)]X where L-2 = bipy, X = BF4 (3) and L-2 = phen, X = PF6 (4); [(eta(5)-indenyl)Ru(PPh3)(2)(L-2)]X where L2 = bipy, X = PF6 (5) and L2 = phen, X = PF6 (6). Complex 6 has been established by single crystal X-ray diffraction analysis. Complex 6 crystallizes in the monoclinic space group P 21/c, with a = 14.6020 (12), b = 12.7100 (17) and c = 18.981 (2) Angstrom, beta = 98.982 (9)degrees, V = 3479.5 (7) Angstrom(3) and Z = 4. These complexes can also be prepared from reactions Of [(eta(5)- Cp*)Ru(PPh3)(2)Cl] (7) and [(eta(5)-indenyl)Ru(PPh3)(2)Cl] (8) with the corresponding ligands in the presence of NH4PF6 or NH4BF4 in toluene. All the complexes were characterized by spectral and analytical data. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01335-9