[(η(5)-C5H5)Os(PPh3)2(DMSO)]BF4 | 934301-55-0

• 英文名称: [(η(5)-C5H5)Os(PPh3)2(DMSO)]BF4
• 英文别名: [CpOs(PPh3)2(DMSO)]BF4
• CAS: 934301-55-0
• 化学式: BF₄*C₄₃H₄₁OOsP₂S
• 分子量: 944.816
• InChiKey: XEFDNGKHJWDYNG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氟硼酸铵 、 (η5-cyclopentadienyl)bis(triphenylphosphine)osmium(II)(Br) 、 二甲基亚砜 以 甲醇 为溶剂， 生成 [(η(5)-C5H5)Os(PPh3)2(DMSO)]BF4
  参考文献：
  名称：

  Reactivity of the [CpM(PPh3)2]+ (M=Ru, Os) fragment with diethyldithiocarbamate

  摘要：

  This paper reports on the reaction of [CpM(PPh3)(2)(L)](+/0)(Cp = eta(5)-C5H5; M = Os, L = CH3CN, DMSO Br; M = Ru, X = Cl, CH3CN) with diethyldithiocarbamate (S2CNEt2-). The exceptional kinetic stability of [Os-PPh3] compared to [Ru-PPh3] is reflected from the isolation of the monodentate diethyldithiocarbamate complex [CpOs(PPh3)(2)(kappa(1)-S2CNEt2)] (3) and the bidentate diethyldithiocarbamate complex [CpRu(PPh3)(kappa(2)-S2CNEt2)] (5) as the only products. The structure of [CpOs(PPh3)(2)(CH3CN)]BF4 (2 center dot BF4) and 5 were determined by X-ray diffraction. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.09.042