| 686719-78-8

• CAS: 686719-78-8
• 化学式: C₁₈H₁₄CrO₃
• 分子量: 330.303
• InChiKey: ODBNLSKHRNBHMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 3,5-二叔丁基邻苯醌 以 四氢呋喃 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Heterocyclisation of ferrocenyl- and benzenetricarbonyl chromium-cyclopentadienes with o-quinone. Evidence for a SET route

  摘要：

  A series of cyclopentadienyl ligands substituted by unsaturated systems including various transition metal groups ((C5H5)(2)Fe, PhCr(CO)(3)) were reacted with 3,5-di-tert-butyl orthoquinone producing 1,4-benzodioxines in high yields. These cycloaddition reactions were stereospecific. H-1 and C-13 NMR studies and X-ray structural analysis are in agreement with the exclusive formation of "endo" cycloadducts. Moreover, an ESR study shows the transient formation of both the radical anion of the o-quinone and the radical cation of the dienic system indicating an alternative single electron transfer pathway. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00482-1
• 作为产物：
  描述：

  tricarbonyl(η6-phenylacetylene)chromium(0) 、 3,4-二甲基-2-环戊酮 在 n-butyl lithium 、 HCl 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以16%的产率得到
  参考文献：
  名称：

  Heterocyclisation of ferrocenyl- and benzenetricarbonyl chromium-cyclopentadienes with o-quinone. Evidence for a SET route

  摘要：

  A series of cyclopentadienyl ligands substituted by unsaturated systems including various transition metal groups ((C5H5)(2)Fe, PhCr(CO)(3)) were reacted with 3,5-di-tert-butyl orthoquinone producing 1,4-benzodioxines in high yields. These cycloaddition reactions were stereospecific. H-1 and C-13 NMR studies and X-ray structural analysis are in agreement with the exclusive formation of "endo" cycloadducts. Moreover, an ESR study shows the transient formation of both the radical anion of the o-quinone and the radical cation of the dienic system indicating an alternative single electron transfer pathway. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00482-1