| 219788-38-2

• CAS: 219788-38-2
• 化学式: C₅₇H₄₇N₆OPRu
• 分子量: 964.084
• InChiKey: XAFMZCLLEALXGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 三苯基胍 以 甲苯 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  N,N′,N″-Triphenylguanidinate(−1) complexes of ruthenium, osmium and iridium: synthesis and X-ray crystal structures

  摘要：

  N,N',N"-Triphenylguanidine (TpgH) reacts with [Ru(H)(2)(CO)(PPh3)(3)] in refluxing toluene and with [Os(H)(2)(CO)(PPh3)(3)] in refluxing o-xylene to yield the guanidinate(- 1) complexes [RuH(Tpg)(CO)(PPh3)(2)] (1) and [Os(Tpg)(2)(CO)(PPh3)] (2), respectively. The reaction of TpgH with [RuCl2(PPh3)(3)] in refluxing toluene affords a new route to the known complex [Ru(Tpg)(2)(CO)(PPh3)] (3). Finally the reaction of mer-[Ir(H)(3)(PPh3)(3)] with TpgH in refluxing toluene yields the iridium(III) dihydride complex [Ir(H)(2)(Tpg)(PPh3)(2)] (4). X-ray crystal structure determinations are reported for (1) and (4). (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00046-3

文献信息

• N,N ′,N ″-Triphenylguanidinate(1−) complexes of ruthenium and palladium: syntheses and crystal structures †
  作者：K. Travis Holman、Stephen D. Robinson、Arvind Sahajpal、Jonathan W. Steed

  DOI：10.1039/a806454g

  日期：——

  N,N′,N″ -Triphenylguanidine (HTpg) reacted with [Ru(O2CCF3)2(CO)(PPh3)2] in boiling toluene to yield [Ru(Tpg)2(CO)(PPh3)], the first example of a mononuclear complex containing two chelate guanidinate(1–) ligands. Palladium(II) acetate reacted with HTpg in warm benzene to form an adduct [Pd(O2CMe)2(HTpg)2] which, under more forcing conditions, converts into the novel binuclear guanidinate(1–) bridged complex [Pd(µ-Tpg)(Tpg)}2]. Crystal structures have been determined for both guanidinate(1–) complexes.

  N,Nâ²,Nâ³Â-三苯基胍（HTpg）与[Ru(O2CCF3)2(CO)(PPh3)2]在沸腾的甲苯中发生反应，生成[Ru(Tpg)2(CO)(PPh3)]，这是第一个含有两个螯合胍（1â）配体的单核络合物实例。醋酸钯（II）与 HTpg 在温热的苯中反应生成加合物 [Pd(O2CMe)2(HTpg)2]，在更苛刻的条件下，该加合物转化为新型双核胍基（1â）桥接复合物 [Pd(µ-Tpg)(Tpg)}2]。两种鸟苷酸（1â）配合物的晶体结构均已确定。