[AuCl((3,5-bis[(dimethylamino)methyl]phenyl)diphenylphosphane)] | 877128-99-9

• 英文名称: [AuCl((3,5-bis[(dimethylamino)methyl]phenyl)diphenylphosphane)]
• CAS: 877128-99-9
• 化学式: C₂₄H₂₉AuClN₂P
• 分子量: 608.901
• InChiKey: KGFTYYAQUOEPKZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [AuCl((3,5-bis[(dimethylamino)methyl]phenyl)diphenylphosphane)] 、 溴甲苯 以 二氯甲烷 为溶剂， 以94%的产率得到[AuCl((3,5-bis[(dimethylamino)methyl]phenyl)diphenylphosphane)]*2(benzyl bromide)
  参考文献：
  名称：

  Synthesis, coordination chemistry, and metal complex reactivity of (dimethylamino)methyl-substituted triarylphosphanes; X-ray study on [AuCl(PPh3−nArn)] (Ar=1-C6H3(CH2NMe2)2-3,5, n=1, 3; Ar=1-C6H4(CH2NMe2)-4, n=3)

  摘要：

  The synthesis of the first series of 4-mono and 3,5-bis(dimethylamino)methyl-functionalized triarylphosphanes of the general formula PPh3-nArn (Ar = 1-C6H3(CH2NMe2)(2)-3,5 (NC(H)N), n = 1 (ligand 2) or n = 3 (ligand 4); Ar = 1 -C6H4(CH2NMe2)-4 (NC(H)), n = 3 (ligand 7)) is described. These phosphanes were used for the construction of complexes of the form [AuCl(P)] and [PtCl2(P)(2)]. In these complexes selective coordination of phosphorus to the metal ion is observed. The P-31 NMR data show the formation of cis-Pt complexes, even in the case of triarylphosphane 4, which features a tris{3,5-bis(dimethylamino)methyl} substitution pattern. The structure of the gold complex of mono-3,5-functionalized triarylphosphane 2 in the solid state shows a striking resemblance to the structure of the corresponding complex [AuCl(PPh3)]. The solid-state structure of the AuCl complex of tris-4-functionalized ligand 7 differs from that of [AuCl(PPh3)] in the sign of the torsion angles. The amine functionalities in this class of gold compounds could be reacted selectively with either acid (HCl, H3PO4) to generate ammonium salts or with an alkylating agent (benzyl bromide) to afford benzyl ammonium salts, without the violation of the Au-P bond. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.09.009
• 作为产物：
  描述：

  {3,5-bis[(dimethylamino)methyl]phenyl}diphenylphosphane 、 (tetrahydrothiophene)gold(I) chloride 以 二氯甲烷 为溶剂， 以93%的产率得到[AuCl((3,5-bis[(dimethylamino)methyl]phenyl)diphenylphosphane)]
  参考文献：
  名称：

  Synthesis, coordination chemistry, and metal complex reactivity of (dimethylamino)methyl-substituted triarylphosphanes; X-ray study on [AuCl(PPh3−nArn)] (Ar=1-C6H3(CH2NMe2)2-3,5, n=1, 3; Ar=1-C6H4(CH2NMe2)-4, n=3)

  摘要：

  The synthesis of the first series of 4-mono and 3,5-bis(dimethylamino)methyl-functionalized triarylphosphanes of the general formula PPh3-nArn (Ar = 1-C6H3(CH2NMe2)(2)-3,5 (NC(H)N), n = 1 (ligand 2) or n = 3 (ligand 4); Ar = 1 -C6H4(CH2NMe2)-4 (NC(H)), n = 3 (ligand 7)) is described. These phosphanes were used for the construction of complexes of the form [AuCl(P)] and [PtCl2(P)(2)]. In these complexes selective coordination of phosphorus to the metal ion is observed. The P-31 NMR data show the formation of cis-Pt complexes, even in the case of triarylphosphane 4, which features a tris{3,5-bis(dimethylamino)methyl} substitution pattern. The structure of the gold complex of mono-3,5-functionalized triarylphosphane 2 in the solid state shows a striking resemblance to the structure of the corresponding complex [AuCl(PPh3)]. The solid-state structure of the AuCl complex of tris-4-functionalized ligand 7 differs from that of [AuCl(PPh3)] in the sign of the torsion angles. The amine functionalities in this class of gold compounds could be reacted selectively with either acid (HCl, H3PO4) to generate ammonium salts or with an alkylating agent (benzyl bromide) to afford benzyl ammonium salts, without the violation of the Au-P bond. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.09.009