| 385831-27-6

• CAS: 385831-27-6
• 化学式: C₁₈H₃₂ClNO₂Ti
• 分子量: 377.791
• InChiKey: ZSHLYVQWOOALGY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (五甲基环戊二烯基)三氯化钛(IV) 、 N-丁基二乙醇胺 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  New half-sandwich metallocene catalysts for polyethylene and polystyrene

  摘要：

  A new type of half-sandwich metallocene catalysts for the polymerization of ethylene and styrene, Cp*MCl(DEA-R) (DEA = (OCH2CH2)(2)N, R = Me, M = Ti (1); R = Me M = Zr (2); R = n-Bu, M = Ti (3)), was prepared by the reaction of corresponding N-alkyl-N,N-diethanolamine with Cp*MCl3 in the presence of triethylamine. Compounds 1-3 are slightly air-sensitive and thermally unstable. All catalyst systems show moderate activities in ethylene polymerization and especially the 2/MMAO system gives PE with broad molecular weight distribution at all polymerization temperatures. In addition, 1/MMAO and 3/MMAO show fairly good activities in sPS polymerization in the order 3/MMAO > 1/MMAO. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01105-6