[n-Bu4N][Mo6Br13(4-vinylpyridine)] | 876861-35-7

• 英文名称: [n-Bu4N][Mo6Br13(4-vinylpyridine)]
• CAS: 876861-35-7
• 化学式: C₇H₇Br₁₃Mo₆N*C₁₆H₃₆N
• 分子量: 1962.0
• InChiKey: ALLLYIUQWOHLBW-UHFFFAOYSA-A

反应信息

• 作为产物：
  描述：

  4-乙烯基吡啶 、 [n-Bu4N]2[Mo6Br13(CF3SO3)] 以 四氢呋喃 为溶剂， 以37%的产率得到[n-Bu4N][Mo6Br13(4-vinylpyridine)]
  参考文献：
  名称：

  From Simple Monopyridine Clusters [Mo₆Br₁₃(Py-R)][n-Bu₄N] and Hexapyridine Clusters [Mo₆X₈(Py-R)₆][OSO₂CF₃]₄ (X = Br or I) to Cluster-Cored Organometallic Stars, Dendrons, and Dendrimers

  摘要：

  Hexasubstitution of apical triflate ligands in the octahedral clusters [M](2)[Mo6X8(CF3SO3)(6)] (M = n-BU4N or Cs, X = Br or 1) and monosubstitution in [n-Bu4N](2)[Mo6Br13(CF3SO3)] was carried out in tetrahydrofuran at 60 degrees C with simple pyridines and then extended to organometallic pyridines, yielding cluster-cored stars, and to dendronic polyallyl and polyferrocenylpyridines, yielding cluster-cored polyallyl and polyferrocenyl dendrimers and dendrons. The orange pyridine-substituted clusters, whose pyridine protons are deshielded in H-1 NMR (a practical tool for characterization), are air-stable and thermally stable with simple pyridines, light- and air-sensitive with organometallic pyridines, and air-fragile and thermally fragile with large dendronized pyridines.

  DOI：

  10.1021/ic051680f