[2,6-[(CH3)C=N(C6H3-2,6-iPr2)2]-C5H3NSnCl]*[SnCl3] | 1361346-23-7

• 英文名称: [2,6-[(CH3)C=N(C6H3-2,6-iPr2)2]-C5H3NSnCl]*[SnCl3]
• 英文别名: [2,6-[(CH₃)C=N(C₆H₃-2,6-iPr₂)₂]-C₅H₃NSnCl]*[SnCl₃]；[(2,6-diacetylpyridinebis(2,6-diisopropylanil)SnCl][SnCl3]
• CAS: 1361346-23-7
• 化学式: C₃₃H₄₃ClN₃Sn*Cl₃Sn
• 分子量: 860.957
• InChiKey: RLLQHGTYQXLJBG-RPBIPJMMSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [2,6-[(CH3)C=N(C6H3-2,6-iPr2)2]-C5H3NSnCl]*[SnCl3] 以 四氢呋喃 、 甲苯 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  N-Coordinated Tin(II) Trifluoromethanesulfonates and Their Reactions with Transition Metal Carbonyls

  摘要：

  The syntheses of the compounds [(LSnCl)-Sn-1][M-(CO)(5)(SnCl3)] (3, M = W; 4, M = Cr), [(LSnCl)-Sn-1]OTf (5), [(LSnCl)-Sn-1][W(CO)(5)(SnCl2OTf)] (6), [(LSnOTf)-Sn-1][OTf] (7), and [(LSn)-Sn-2(OTf)(2)] (8) with L-1 = {2,6-[(CH3)C=N(C6H3-2,6-Pr-i(2))(2)]C5H3N} (DIMPY) and L-2 = {2-[(CH3)C=N-(C6H3-2,6-Pr-i(2))]-6-(CH3O)}C5H3N) is reported. The compounds were characterized by elemental analyses, H-1, C-13, F-19, and Sn-119 NMR spectroscopy, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction analyses (3 center dot 1.5C(7)H(8), 5 center dot CH2Cl2, 7 center dot C7H8, 8). For compounds 7 and 8, the experimental work is accompanied by density functional theory calculations.

  DOI：

  10.1021/acs.inorgchem.5b00678
• 作为产物：
  描述：

  2,6-双[1-(2,6-二异丙苯亚氨基)乙基]吡啶 、 tin(ll) chloride 以 甲苯 为溶剂， 以85%的产率得到[2,6-[(CH3)C=N(C6H3-2,6-iPr2)2]-C5H3NSnCl]*[SnCl3]
  参考文献：
  名称：

  Lewis Base Mediated Autoionization of GeCl₂and SnCl₂

  摘要：

  Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl+) and anionic (MCl3-) species of heavier low-valent group 14 elements of germanium(II) and tin(II) by using the substituted Schiff base 2,6-diacetylpyridinebis(2,6-diisopropylanil) as Lewis base (LB). Treatment of LB with 2 equiv of GeCl2 center dot dioxane and SnCl2 in toluene gives compounds [(LB)(GeCl)-Cl-II](+)[(GeCl3)-Cl-II](-) (1) and [(LB)(SnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) (2), respectively, which possess each a low-valent cation and an anion. Compounds 1 and 2 are well characterized with various spectroscopic methods and single crystal X-ray structural analysis.

  DOI：

  10.1021/ja300563g

文献信息

• Role of the Trichlorostannyl Ligand in Tin–Ruthenium Arene Complexes: Experimental and Computational Studies
  作者：Miroslav Novák、Marek Bouška、Libor Dostál、Michael Lutter、Klaus Jurkschat、Jan Turek、Frank De Proft、Zdeňka Růžičková、Roman Jambor

  DOI：10.1002/ejic.201700098

  日期：2017.3.3

  and ionic ruthenium arene trichlorostannyl complexes is reported. The tin(II) compounds L1SnCl (1, L1 = [2-(CH2NEt2)-4,6-(tBu)2C6H2]-) and [L2SnCl][SnCl3] (2, L2 = 2,6-[(CH3)C=N(C6H3-2,6-iPr2)2]C5H3N) show a rather different reactivity towards the ruthenium complex [(6-cymene)RuCl]2(-Cl)2. As a consequence, the neutral complex [Ru(6-cymene)(L1SnCl)Cl2] (4) and the ionic compound [L2SnCl][Ru(6-cymene)(SnCl3)2Cl]

  报道了一组中性和离子钌芳烃三氯甲锡基配合物。锡 (II) 化合物 L1SnCl (1, L1 = [2-(CH2NEt2)-4,6-(tBu)2C6H2]-) 和 [L2SnCl][SnCl3] (2, L2 = 2,6-[(CH3) C=N(C6H3-2,6-iPr2)2]C5H3N) 对钌络合物 [(6-cymene)RuCl]2(-Cl)2 显示出相当不同的反应性。结果，中性配合物[Ru(6-伞花烃)(L1SnCl)CL2](4)和离子化合物[L2SnCl][Ru(6-伞花烃)(SnCl3)2Cl](8)被分离出来。4 与 SnCL2 的插入反应提供了中性的三金属钌配合物 [Ru(6-cymene)(L1SnCl)(SnCl3)Cl] (6)。类似的钌配合物 [Ru(6-cymene)(L3PPh2)CL2] (5) 和 [Ru(6-cymene)(L3PPh2)(SnCl3)Cl]