trichloro[methylenebis(diphenylphosphine oxide-O)]antimony | 26950-31-2

• 英文名称: trichloro[methylenebis(diphenylphosphine oxide-O)]antimony
• CAS: 26950-31-2
• 化学式: C₂₅H₂₂Cl₃O₂P₂Sb
• 分子量: 644.505
• InChiKey: QLMLIWGEPXRZHE-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化锑(V) 、 双二苯基膦甲烷 以 乙腈 为溶剂， 生成 trichloro[methylenebis(diphenylphosphine oxide-O)]antimony
  参考文献：
  名称：

  Trichloro[methylenebis(diphenylphosphine oxide-O)]antimony(III)

  摘要：

  The asymmetric unit of the title complex, [SbCl3{[(C6H5)(2)PO](2)CH2}], comprises two independent molecules, in both of which the Sb atoms are in flattened square-pyramidal environments, with the basal planes each defined by two O and two Cl atoms, and the apical atom being Cl in each molecule. The geometry can alternatively be described as distorted octahedral as a result of coordination by a sixth (Cl) atom at a longer distance.

  DOI：

  10.1107/s0108270198012335