ferrocenylamidoundecanoic acid | 1111735-43-3

• 英文名称: ferrocenylamidoundecanoic acid
• 英文别名: (η5-cyclopentadienyl)Fe(η5-C5H4CONH(CH2)10COOH)
• CAS: 1111735-43-3
• 化学式: C₂₂H₃₁FeNO₃
• 分子量: 413.34
• InChiKey: CVTDAGUHLIIGOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三聚氟氰 、 ferrocenylamidoundecanoic acid 在 pyridine 作用下， 以 二氯甲烷 为溶剂， 以91%的产率得到ferrocenylamidoundecanoic acid fluoride
  参考文献：
  名称：

  Anion Receptor Electrochemical Sensing Properties of Poly(propyleneimine) Dendrimers with Ferrocenylamidoalkyl Terminal Groups

  摘要：

  A novel family of dendrimers with amidoferrocenyl units attached to diaminobutane-based poly(propyleneimine) surfaces through alkyl chains, DAB-dend-[NHCO(CH2)(10)HNCOFc](x) (3-6: x = 4, 8, 16, 32), Fc = [eta(5)-C5H5]Fe[eta(5)-C5H4], has been prepared by reaction of the novel functionalized ferrocenyl derivative [eta 5-C5H5]Fe[eta(5)-C5H4CONH(CH2)(10)COF] (2) with the corresponding amine dendrimers. Characterization of the synthesized dendrimers by H-1 and C-13{H-1} NMR and IR spectroscopy and mass spectrometry supports their assigned structures. The redox activity of the ferrocenyl centers in 3-6 has been characterized by cyclic voltammetry. These compounds showed electrochemical responses to the anions not only in organic solvents but also immobilized onto electrode surfaces in organic and aqueous media. Selective recognition for H2PO4- over other anions was observed.

  DOI：

  10.1021/om8007019
• 作为产物：
  描述：

  fluorocarbonylferrocene 、 11-氨基十一酸 以 四氢呋喃 为溶剂， 以60%的产率得到ferrocenylamidoundecanoic acid
  参考文献：
  名称：

  Anion Receptor Electrochemical Sensing Properties of Poly(propyleneimine) Dendrimers with Ferrocenylamidoalkyl Terminal Groups

  摘要：

  A novel family of dendrimers with amidoferrocenyl units attached to diaminobutane-based poly(propyleneimine) surfaces through alkyl chains, DAB-dend-[NHCO(CH2)(10)HNCOFc](x) (3-6: x = 4, 8, 16, 32), Fc = [eta(5)-C5H5]Fe[eta(5)-C5H4], has been prepared by reaction of the novel functionalized ferrocenyl derivative [eta 5-C5H5]Fe[eta(5)-C5H4CONH(CH2)(10)COF] (2) with the corresponding amine dendrimers. Characterization of the synthesized dendrimers by H-1 and C-13{H-1} NMR and IR spectroscopy and mass spectrometry supports their assigned structures. The redox activity of the ferrocenyl centers in 3-6 has been characterized by cyclic voltammetry. These compounds showed electrochemical responses to the anions not only in organic solvents but also immobilized onto electrode surfaces in organic and aqueous media. Selective recognition for H2PO4- over other anions was observed.

  DOI：

  10.1021/om8007019