[(η5-C5H5)Fe(CO)(C(O)Me)PPhPy2] | 940281-77-6

• 英文名称: [(η5-C5H5)Fe(CO)(C(O)Me)PPhPy2]
• CAS: 940281-77-6
• 化学式: C₂₄H₂₁FeN₂O₂P
• 分子量: 456.264
• InChiKey: SCLIYAKPESIFDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dicarbonyl(cyclopentadienyl)methyliron(II) 、 2,2'-(苯基膦二基)二吡啶 以 四氢呋喃 为溶剂， 以48%的产率得到[(η5-C5H5)Fe(CO)(C(O)Me)PPhPy2]
  参考文献：
  名称：

  Electron-transfer chain catalysis in phosphine replacement reaction: Determination of relative donor capability of arylpyridylphosphines

  摘要：

  The slight differences in the donor capabilities of PPhnPy3-n (n = 0-3) could be measured directly in the equilibrium of phosphine replacement reaction on (eta(5)-C5H5)Fe(CO)(2)-phosphine complexes, taking advantage of the radical pathway to establish equilibrium rapidly. The simultaneous determination of equilibrium constants is done in a single experiment. The donor capability increases in the order PPh3 < PPh2Py < PPhPy2 < PPy3 with quantified (eta(5)-C5H5)Fe(CO)(2)(+)-affinity scales at 1, 4.90, 11.0, and 20.3, respectively. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.12.051