{(dppe)(η-C6H6)ReH} | 142196-02-9

• 英文名称: {(dppe)(η-C6H6)ReH}
• CAS: 142196-02-9
• 化学式: C₃₂H₃₁P₂Re
• 分子量: 663.753
• InChiKey: AKAONIMFCYMUEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氟硼酸-二乙醚络合物 、 {(dppe)(η-C6H6)ReH} 以 乙醚 为溶剂， 以98%的产率得到{(dppe)(η-C6H6)ReH2}{BF4}
  参考文献：
  名称：

  Photochemical reactions of [(Ph3P)2ReH7] and [(Ph2PCH2CH2PPh2)ReH7]

  摘要：

  [(Ph3P)2ReH7] (Ia) reacted in tetrahydrofuran with cyclopentadiene or cyclohexa-1,4-diene under UV irradiation to give [(Ph3P)(eta-C5H5)ReH4] (II), and a 1:2 mixture of [(Ph3P)2(eta-C6H6)ReH] and [(Ph3P)(eta-C6H6)ReH3] (III), respectively; III was isolated from the photochemical reaction of Ia with 3,3-dimethylbutene in benzene. When using [(dppe)ReH7] (Ib) (dppe = Ph2PCH2CH2PPh2) instead of Ia in these three reactions, no cyclopentadienyl compound was obtained, but [(dppe)(eta-C6H6)ReH] (IV) and [(dppe)(eta-C6H6)ReCH2CH2CMe3] (V) were isolated; IV and V are precursors to arene and cyclohexadienylrhenium derivatives containing dppe.

  DOI：

  10.1016/0022-328x(92)80072-6
• 作为产物：
  描述：

  1,2-bis(diphenylphosphino)ethane rhenium heptahydride 在 1,4-环己二烯 作用下， 以 四氢呋喃 为溶剂， 生成 {(dppe)(η-C6H6)ReH}
  参考文献：
  名称：

  Photochemical reactions of [(Ph3P)2ReH7] and [(Ph2PCH2CH2PPh2)ReH7]

  摘要：

  [(Ph3P)2ReH7] (Ia) reacted in tetrahydrofuran with cyclopentadiene or cyclohexa-1,4-diene under UV irradiation to give [(Ph3P)(eta-C5H5)ReH4] (II), and a 1:2 mixture of [(Ph3P)2(eta-C6H6)ReH] and [(Ph3P)(eta-C6H6)ReH3] (III), respectively; III was isolated from the photochemical reaction of Ia with 3,3-dimethylbutene in benzene. When using [(dppe)ReH7] (Ib) (dppe = Ph2PCH2CH2PPh2) instead of Ia in these three reactions, no cyclopentadienyl compound was obtained, but [(dppe)(eta-C6H6)ReH] (IV) and [(dppe)(eta-C6H6)ReCH2CH2CMe3] (V) were isolated; IV and V are precursors to arene and cyclohexadienylrhenium derivatives containing dppe.

  DOI：

  10.1016/0022-328x(92)80072-6