| 1426679-74-4

• CAS: 1426679-74-4
• 化学式: C₄₃H₄₂F₆GaN
• 分子量: 756.527
• InChiKey: QJIYIQULSFMISW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  C₂₉H₃₄Br₂GaN 、 4-三氟甲基苯硼酸 在 caesium carbonate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 2-二环己基磷-2,4,6-三异丙基联苯 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以79%的产率得到
  参考文献：
  名称：

  Synthesis and Optical Properties of Stable Gallafluorene Derivatives: Investigation of Their Emission via Triplet States

  摘要：

  We designed and synthesized air- and moisture-stable gallafluorenes in which two benzene rings were bridged by the four-coordinate gallium atoms. The series of gallafluorenes were prepared by introducing electron-donating and -withdrawing groups through Suzuki-Miyaura coupling reactions. The gallafluorenes showed unique emissions via their triplet states in the presence of B(C6F5)(3). These emissions were obtained via the triplet exciplex of gallafluorene and B(C6F5)(3).

  DOI：

  10.1021/ja400287y