(η3-2-methylallyl)Ru(CO)3Cl | 114925-38-1

• 英文名称: (η3-2-methylallyl)Ru(CO)3Cl
• 英文别名: RuCl(η3-C3H4CH3)(CO)
• CAS: 114925-38-1
• 化学式: C₇H₇ClO₃Ru
• 分子量: 275.654
• InChiKey: GOKWLXFILNFTAR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,1'-bis(diisopropylphosphino)ferrocene 、 (η3-2-methylallyl)Ru(CO)3Cl 以 四氢呋喃 为溶剂， 以69%的产率得到RuCl(η3-C3H4CH3)(CO)(1,1'-bis(diisopropylphosphino)ferrocene)
  参考文献：
  名称：

  An Easy Entry to Dimers [{RuX(μ-X)(CO)(P⌒P)}₂] (X = Cl, Br; P⌒P = 1,1‘-Bis(diphenylphosphino)ferrocene, 1,1‘-Bis(diisopropylphosphino)ferrocene) from η³-Allylruthenium(II) Derivatives [RuX(η³-2-C₃H₄R)(CO)(P⌒P)] (R = H, Me):  Efficient Catalyst Precursors in Transfer Hydrogenation of Ketones

  摘要：

  Complexes [RuX(eta(3)-2-C3H4R)(CO)(P<^>P)] (X = Cl, Br; R = H, Me; P<^>P = dppf, dippf) (2a-d and 3a-d) have been prepared by reaction of the eta-allylruthenium(II) derivatives [RuX(eta(3)-2-C3H4R)(CO)(3)] (1a-d) with 1 equiv of the appropriate diphosphine. Treatment of 2a-d and 3a-d with HX allows the high-yield preparation of the dimeric compounds [{RUX(mu-X)(CO)(P<^>P) }(2)] (P<^>P = dppf, X = Cl (4a), Br (4b); P<^>P = dippf, X = Cl (5a), Br (5b)). Complex [{RuCl(mu-Cl)(CO)(dppf)}(2)] reacts with neutral ligands, via chloride bridge cleavage, affording the mononuclear derivatives [RuCl2(CO)(L)(dppf)] (L = CO (6a), BzNC (6b), Py (6c), PhNH2 (6d)). The structures of compounds [RUCl(eta(3)-C3H5)(CO)(dPPf)] (2a), [{RuCl(mu-Cl)(CO)(dppf)}(2)] (4a), and [RuCl2(CO)(Py)(dppf)] (6c) have been confirmed by X-ray crystallography. The catalytic activity of dimers 4a,b and 5a,b in transfer hydrogenation of ketones by propan-2-ol has also been studied.

  DOI：

  10.1021/om030530e
• 作为产物：
  描述：

  十二羰基三钌 、 3-氯-2-甲基丙烯 以 异辛烷 为溶剂， 生成 (η3-2-methylallyl)Ru(CO)3Cl
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 198, page 530 - 532

  摘要：

  DOI：

文献信息

• Wuu, Yee-Min; Wrighton, Mark S., Organometallics, 1988, vol. 7, # 8, p. 1839 - 1845
  作者：Wuu, Yee-Min、Wrighton, Mark S.

  DOI：——

  日期：——
• Green, Malcolm L. H.; Popham, Neil H., Journal of the Chemical Society, Dalton Transactions, 1999, # 7, p. 1049 - 1059
  作者：Green, Malcolm L. H.、Popham, Neil H.

  DOI：——

  日期：——
• Sbrana, G.; Braca, G.; Piacenti, F., Journal of Organometallic Chemistry, 1968, vol. 13, p. 240 - 242
  作者：Sbrana, G.、Braca, G.、Piacenti, F.、Pino, P.

  DOI：——

  日期：——