Rh[bis(4-tert-butylphenyl)-2-pyridylmethanethiolate(1-)](1,5-cyclooctadiene) | 195820-98-5

• 英文名称: Rh[bis(4-tert-butylphenyl)-2-pyridylmethanethiolate(1-)](1,5-cyclooctadiene)
• CAS: 195820-98-5
• 化学式: C₃₄H₄₂NRhS
• 分子量: 599.686
• InChiKey: AHJQAXAIXSPOHE-GHDUESPLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Rh[bis(4-tert-butylphenyl)-2-pyridylmethanethiolate(1-)](1,5-cyclooctadiene) 、 一氧化碳 以 氘代苯 为溶剂， 生成 Rh[bis(4-tert-butylphenyl)-2-pyridylmethanethiolate(1-)](CO)2
  参考文献：
  名称：

  Syntheses and electrochemistry of metal complexes of a bulky pyridine-thiolate ligand

  摘要：

  Reactions of Li(tBuL-NS) (lithium bis(4-t-butylphenyl)-2-pyridylmethanthiolate(1-)) with MCl2 (M = Ni, Zn, Pt) afforded the respective M(tBuL-NS)(2) complexes in good yields. Treatment of CuCl2, Cu(OTf)(2) (OTf = triflate) and PdCl2(PhCN)(2) with Li(tBuL-NS) led to the formation of the dimeric compounds [Cu(tBuL-NS)Cl](2) . 2H(2)O, Cu-2(tBuL-NS)(3)(OTf) and [Pd(tBuL-NS)Cl](2), respectively. The interaction df Li-(t-BuL-NS) with [Ru(CO)(2)Cl-2](n), [Rh(COD)Cl](2) (COD = 1,5-cyclooctadiene) and Re(CO)(5)Cl gave cis-Ru(tBuL-NS)(2)(CO)(2), Rh(tBuL-NS)(COD) and Re(tBuL-NS)(CO)(4), respectively. The structure of Rh(tBuL-NS)(COD) has been established by X-ray crystallography. The geometry around Rh is square planar with Rh-N and Rh-S distances of 2.114 (5) and 2.250 (2) Angstrom, respectively. Reaction of Ni(PMe3)(2)(CH3)Cl with Li(tBuL-NS) afforded Ni(tBuL-NS)(PMe3)CH3, which undergoes CO insertion to give the acyl complex Ni(tBuL-NS) (PMe3)(COCH3). The cyclic voltammogram of Pt(tBuL-NS)(2) exhibits a reversible 1-electron couple al 0.3 V vs ferrocenium-ferrocene, which is assigned as the ligand-centered oxidation. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00098-3
• 作为产物：
  描述：

  di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 、 lithium bis(4-tert-butylphenyl)-2-pyridylmethanethiolate 以 四氢呋喃 为溶剂， 以50%的产率得到Rh[bis(4-tert-butylphenyl)-2-pyridylmethanethiolate(1-)](1,5-cyclooctadiene)
  参考文献：
  名称：

  Syntheses and electrochemistry of metal complexes of a bulky pyridine-thiolate ligand

  摘要：

  Reactions of Li(tBuL-NS) (lithium bis(4-t-butylphenyl)-2-pyridylmethanthiolate(1-)) with MCl2 (M = Ni, Zn, Pt) afforded the respective M(tBuL-NS)(2) complexes in good yields. Treatment of CuCl2, Cu(OTf)(2) (OTf = triflate) and PdCl2(PhCN)(2) with Li(tBuL-NS) led to the formation of the dimeric compounds [Cu(tBuL-NS)Cl](2) . 2H(2)O, Cu-2(tBuL-NS)(3)(OTf) and [Pd(tBuL-NS)Cl](2), respectively. The interaction df Li-(t-BuL-NS) with [Ru(CO)(2)Cl-2](n), [Rh(COD)Cl](2) (COD = 1,5-cyclooctadiene) and Re(CO)(5)Cl gave cis-Ru(tBuL-NS)(2)(CO)(2), Rh(tBuL-NS)(COD) and Re(tBuL-NS)(CO)(4), respectively. The structure of Rh(tBuL-NS)(COD) has been established by X-ray crystallography. The geometry around Rh is square planar with Rh-N and Rh-S distances of 2.114 (5) and 2.250 (2) Angstrom, respectively. Reaction of Ni(PMe3)(2)(CH3)Cl with Li(tBuL-NS) afforded Ni(tBuL-NS)(PMe3)CH3, which undergoes CO insertion to give the acyl complex Ni(tBuL-NS) (PMe3)(COCH3). The cyclic voltammogram of Pt(tBuL-NS)(2) exhibits a reversible 1-electron couple al 0.3 V vs ferrocenium-ferrocene, which is assigned as the ligand-centered oxidation. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00098-3