N,N-di(2,6-methyl)phenylformamidine gold(I) chloride | 1345545-57-4

• 英文名称: N,N-di(2,6-methyl)phenylformamidine gold(I) chloride
• CAS: 1345545-57-4
• 化学式: C₁₇H₂₀AuClN₂
• 分子量: 484.779
• InChiKey: JIPAYDXBPSHLDW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 N,N'-bis-2,6-xylylformamidine 以 乙腈 为溶剂， 以72.2%的产率得到N,N-di(2,6-methyl)phenylformamidine gold(I) chloride
  参考文献：
  名称：

  Two new mononuclear gold(I)–nitrogen [N,N′-di(2,6-methyl)phenylformamidine] complexes: Syntheses and crystal structures

  摘要：

  Two gold(I) mononuclear complexes have been prepared by reacting gold(I) tetrahydrothiophene with N,N'-di(2,6-methyl)phenylformamidine. The neutral complex [N,N'-di(2,6-methyl) phenylformamidine)-gold(I) chloride (C17H20AuClN2) (1), crystallizes in the triclinic group P (1) over bar while the cationic [N,N'-di(2,6-methyl)phenylformamidine](tetrahydrothiophene)-gold(I) (C21H28AuN2S) (2) crystallizes with a nitrate anion in the monoclinic group P2(1)/n. Both compounds are good starting materials for synthetic gold chemistry. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.08.013