[Cu2(2-hydroxypyridine(-1H))2(1,2-bis(diphenylphosphino)methane)]2 | 888015-35-8

• 英文名称: [Cu2(2-hydroxypyridine(-1H))2(1,2-bis(diphenylphosphino)methane)]2
• CAS: 888015-35-8
• 化学式: C₇₀H₆₀Cu₄N₄O₄P₄
• 分子量: 1399.35
• InChiKey: NIJSBFUVOPVKCJ-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  双二苯基膦甲烷 、 2-羟基吡啶 、 copper (I) tert-butoxide 以 四氢呋喃 为溶剂， 以68%的产率得到[Cu2(2-hydroxypyridine(-1H))2(1,2-bis(diphenylphosphino)methane)]2
  参考文献：
  名称：

  Synthesis, structures and reactivity of N-donor-functionalised Cu(I) aryloxides

  摘要：

  The preparation and characterisation of the Cu(I) aryloxides [Cu-16(3-pyO)(16)(dppm)(8)] (1), [(Cu-2(2-pyO)(2)(dPPM)}(2)](2) and [{Cu-3(mu(3)-6 OQ)(2)(dppm)(3)}{(6-HOQ)(2)(mu-6-OQ)}] (3) (dppm = 1,2-bis-diphenylphosphinomethane, 6-HOQ = 6-hydroxyquinoline, py = pyridine) are described. A first attempt to employ organic anhydrides in insertion reactions with Cu(I) aryloxides was made producing the one-dimensional coordination polymer 1/infinity[Cu-3(3-pyO)(CO(2)C(2)H(4)Boc)(dppm(-))(dppm)]infinity (4) (Boc = tert-butoxycarbonyl). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.12.017