(Z)-1-[2-(triphenylstannyl)vinyl]-1-cycloheptanol | 165679-64-1

• 英文名称: (Z)-1-[2-(triphenylstannyl)vinyl]-1-cycloheptanol
• CAS: 165679-64-1
• 化学式: C₂₇H₃₀OSn
• 分子量: 489.245
• InChiKey: GCDKLWVMKNZTTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (Z)-1-[2-(triphenylstannyl)vinyl]-1-cycloheptanol 、 一氯化碘 以 四氯化碳 为溶剂， 以86%的产率得到(Z)-1-[2-(chlorodiphenylstannyl)vinyl]-1-cycloheptanol
  参考文献：
  名称：

  (Z)-1-[2-(Triarylstannyl)vinyl]-1-cycloheptanols: Synthesis, characterization, halodemetallation and crystal structures

  摘要：

  The synthesis and characterization by H-1, C-13, Sn-119 Mossbauer spectroscopy of (Z)-1-[2-(triphenylstannyl)vinyl]-1-cycloheptanol, CH2(CH2)(5)C(OH)CH=CHSnPh(3) (1), and (Z)-1-[2-(tri-p-tolylstannyl)vinyl]-1-cycloheptanol, CH2(CH2)(5)C(OH)CH=CHSn(p-tol)(3) (2), are described, together with their halodemetallation by I-2, Br-2 and ICI1 to yield derivatives of the types CH2(CH2)(5)C(OH)CH=CHSnAr(3-n)X(n) (Ar = phenyl or p-tolyl, n = 1, 2; X = I, Br, CI, respectively). The solid-state structures of four compounds been determined by X-ray diffraction analysis. In the crystals of CH2(CH2)(5)C(OH)CH=CHSnPh(3) (1) and CH2(CH2)(5)C(OH)CH=CHSn(p-tol)(3) (2) the Sn atom has a tetrahedral geometry distorted towards trigonal bipyramid as a consequence of a close intramolecular contact with the hydroxyl O(1) atom of 2.742(3) Angstrom and 2.768(3) Angstrom respectively. A trigonal bipyramidal geometry is found in CH2(CH2)(5)C(OH)CH=CHSn(p-tol)Br-2 (12) and CH2(CH2)(5)C(OH)CH=CHSn(p-tol)(2)Cl (4), in which significant Sn-O(1) interactions are noted [2.437(8) Angstrom and 2.407(8) Angstrom, respectively].

  DOI：

  10.1016/0022-328x(95)05170-t
• 作为产物：
  描述：

  1-乙炔-1-环庚醇 、 三苯基氢化锡 在 dibenzoyl peroxide 作用下， 以 乙醚 为溶剂， 以63%的产率得到(Z)-1-[2-(triphenylstannyl)vinyl]-1-cycloheptanol
  参考文献：
  名称：

  (Z)-1-[2-(Triarylstannyl)vinyl]-1-cycloheptanols: Synthesis, characterization, halodemetallation and crystal structures

  摘要：

  The synthesis and characterization by H-1, C-13, Sn-119 Mossbauer spectroscopy of (Z)-1-[2-(triphenylstannyl)vinyl]-1-cycloheptanol, CH2(CH2)(5)C(OH)CH=CHSnPh(3) (1), and (Z)-1-[2-(tri-p-tolylstannyl)vinyl]-1-cycloheptanol, CH2(CH2)(5)C(OH)CH=CHSn(p-tol)(3) (2), are described, together with their halodemetallation by I-2, Br-2 and ICI1 to yield derivatives of the types CH2(CH2)(5)C(OH)CH=CHSnAr(3-n)X(n) (Ar = phenyl or p-tolyl, n = 1, 2; X = I, Br, CI, respectively). The solid-state structures of four compounds been determined by X-ray diffraction analysis. In the crystals of CH2(CH2)(5)C(OH)CH=CHSnPh(3) (1) and CH2(CH2)(5)C(OH)CH=CHSn(p-tol)(3) (2) the Sn atom has a tetrahedral geometry distorted towards trigonal bipyramid as a consequence of a close intramolecular contact with the hydroxyl O(1) atom of 2.742(3) Angstrom and 2.768(3) Angstrom respectively. A trigonal bipyramidal geometry is found in CH2(CH2)(5)C(OH)CH=CHSn(p-tol)Br-2 (12) and CH2(CH2)(5)C(OH)CH=CHSn(p-tol)(2)Cl (4), in which significant Sn-O(1) interactions are noted [2.437(8) Angstrom and 2.407(8) Angstrom, respectively].

  DOI：

  10.1016/0022-328x(95)05170-t