[(η5-cyclopentadienyl)Fe(η5-C5H4CH2NHCH2C6H4Cl-4)] | 913170-98-6

• 英文名称: [(η5-cyclopentadienyl)Fe(η5-C5H4CH2NHCH2C6H4Cl-4)]
• CAS: 913170-98-6
• 化学式: C₁₈H₁₈ClFeN
• 分子量: 339.648
• InChiKey: DVOAACCVTWDOGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 [(η5-cyclopentadienyl)Fe(η5-C5H4CH2NHCH2C6H4Cl-4)] 在 sodium cyanoborohydride 作用下， 以 水 、 溶剂黄146 为溶剂， 以72%的产率得到[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4Cl-4)]
  参考文献：
  名称：

  Activation of the CH bond in [(η5-C5H5)Fe(η5-C5H4CH2N(CH3)CH2C6H4R-4)] induced by platinum (II): Crystal structure of σ-Pt[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4OCH3-4)]Cl(DMSO)

  摘要：

  Condensations of ferrocenylcarboxaldehyde (1) and p-methyl (2b) or p-chlorobenzylamines (2d) in methanol resulted in ferrocenylaldimines 3b, d which were reduced by lithium aluminum hydride to give 4b, d, respectively. Reductive methylations of 4b, d with aqueous formaldehyde, sodium cyanoborohydride and acetic acid afforded the tertiary ferrocenylamines 5b, d. Treatment of 5a-e [(eta(5)-C5H5)Fe(eta(5)-C5H4CH2N(CH3)CH2C6H4R-4)] (R = CH3O(a), CH3(b), H(c), Cl(d), NO2(e)) with cis-[Pt(DMSO)(2)Cl-2] in methanol produced predominately cycloplatinated complexes 6a-e sigma-Pt[(eta(5)-C5H5)Fe(eta(5)-C5H3CH2N(CH3)CH2C6H4-R-4)]Cl(DMSO) (R = same as before) in which the configurations consisted of RNRP and SNSP, In addition, the preferred activation of the C-H bond in the cyclopentadienyl ring rather than that in the phenyl ring was also observed. All compounds 3b-5b, 3d-5d, 6a-e were characterized by elemental analysis, IR and H-1 NMR. The structure of 6a was determined by X-ray single crystal diffraction. The possible mechanism for the formation of 6 was discussed. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.02.017
• 作为产物：
  描述：

  4'-chlorobenzyl-ferrocenylcarboxaldimine 、 lithium aluminium tetrahydride 以 四氢呋喃 为溶剂， 以80%的产率得到[(η5-cyclopentadienyl)Fe(η5-C5H4CH2NHCH2C6H4Cl-4)]
  参考文献：
  名称：

  Activation of the CH bond in [(η5-C5H5)Fe(η5-C5H4CH2N(CH3)CH2C6H4R-4)] induced by platinum (II): Crystal structure of σ-Pt[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4OCH3-4)]Cl(DMSO)

  摘要：

  Condensations of ferrocenylcarboxaldehyde (1) and p-methyl (2b) or p-chlorobenzylamines (2d) in methanol resulted in ferrocenylaldimines 3b, d which were reduced by lithium aluminum hydride to give 4b, d, respectively. Reductive methylations of 4b, d with aqueous formaldehyde, sodium cyanoborohydride and acetic acid afforded the tertiary ferrocenylamines 5b, d. Treatment of 5a-e [(eta(5)-C5H5)Fe(eta(5)-C5H4CH2N(CH3)CH2C6H4R-4)] (R = CH3O(a), CH3(b), H(c), Cl(d), NO2(e)) with cis-[Pt(DMSO)(2)Cl-2] in methanol produced predominately cycloplatinated complexes 6a-e sigma-Pt[(eta(5)-C5H5)Fe(eta(5)-C5H3CH2N(CH3)CH2C6H4-R-4)]Cl(DMSO) (R = same as before) in which the configurations consisted of RNRP and SNSP, In addition, the preferred activation of the C-H bond in the cyclopentadienyl ring rather than that in the phenyl ring was also observed. All compounds 3b-5b, 3d-5d, 6a-e were characterized by elemental analysis, IR and H-1 NMR. The structure of 6a was determined by X-ray single crystal diffraction. The possible mechanism for the formation of 6 was discussed. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.02.017