(1N-(2-pyridyl-2-methyl)-2-phenylazo anilinate) palladium(II) chloride] | 913059-40-2

• 英文名称: (1N-(2-pyridyl-2-methyl)-2-phenylazo anilinate) palladium(II) chloride]
• CAS: 913059-40-2
• 化学式: C₁₈H₁₅ClN₄Pd
• 分子量: 429.217
• InChiKey: DFGNKSVBGZQFCV-ZPZFBZIMSA-M

反应信息

• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 1N-(2-pyridyl-2-methyl)-2-phenylazo aniline 以 甲醇 为溶剂， 以55%的产率得到(1N-(2-pyridyl-2-methyl)-2-phenylazo anilinate) palladium(II) chloride]
  参考文献：
  名称：

  Syntheses, characterisation and structure of new diazoketiminato chelates of palladium(II) incorporating a tridentate (N,N,N) azo ligand

  摘要：

  The 1N-(2-pyridyl-2-methyl)-2-arylazo aniline, HL [where HL = ArN=NC6H4N(H)(CH2C5H4N); Ar=C6H5 (for HL1) or p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)], ligands were prepared by treating the appropriate 2-(arylazo) aniline with 2-chloromethyl pyridine. Reactions of Na2PdCl4 with HL afforded (L)PdCl complexes. HL binds palladium(II) in a tridentate fashion (N,N,N) forming a new diazoketiminato chelate, dissociating the amino proton. The X-ray structure of (L-1)PdCl was determined. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.03.019