[Cu4(2,2'-bipyridine)4(H2O)2(PO4)2](H3O)[PMo12O40] | 848644-13-3

• 英文名称: [Cu4(2,2'-bipyridine)4(H2O)2(PO4)2](H3O)[PMo12O40]
• CAS: 848644-13-3
• 化学式: C₄₀H₃₆Cu₄N₈O₁₀P₂*H₃O*Mo₁₂O₄₀P
• 分子量: 2946.16
• InChiKey: SNGJJXXRCIYCMD-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 sodium molybdate dihydrate 、 磷酸 、 copper(II) acetate monohydrate 以 水 为溶剂， 以50%的产率得到[Cu4(2,2'-bipyridine)4(H2O)2(PO4)2](H3O)[PMo12O40]
  参考文献：
  名称：

  Hydrothermal synthesis and crystal structure of a hybrid material based on [Cu4(bpy)4(H2O)2(PO4)2]2+ and an α-Keggin polyoxoanion

  摘要：

  A unique composite hybrid material [Cu-4(bpy)(4)(H2O)(2)(PO4)(2)](H3O)[PMo12O40] 1 (bpy = 2, 2'-bipyridine) has been hydrothermally synthesized from the reaction of Na2MoO4.2H(2)O, H3PO4, Cu(MeCO2)(2) . H2O, 2, 2'-bpy and water. It has been characterized by elemental analysis, IR, TG, and single-crystal X-ray diffraction. Compound 1 is constructed from the organic-inorganic hybrid [CU4(bpy)(4)(H2O)(2) (PO4)(2)](2+) cation and alpha-Keggin [PMo12O40](3-) polyoxoanion, which represents the first example of a hybrid material that combines transition metal phosphate and polyoxometalate. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.10.061