[κ2(P,F)-PiPr2(C6H4(2-BF3))Ni(η3-allyl)(acetonitrile-d3)] | 1438644-11-1

• 英文名称: [κ2(P,F)-PiPr2(C6H4(2-BF3))Ni(η3-allyl)(acetonitrile-d3)]
• 英文别名: [κ²(P,F)-PⁱPr₂(C₆H₄(2-BF₃))Ni(η³-allyl)(NCCD₃)]；[κ²(P,F)-PⁱPr₂(C₆H₄(2-BF₃))Ni(η³-allyl)(acetonitrile-d₃₎]
• CAS: 1438644-11-1
• 化学式: C₁₇H₂₆BF₃NNiP
• 分子量: 404.846
• InChiKey: GKKCUDGUHIOFRE-ASTPDCTMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  PHiPr2(2-BF3-Ph) 以 四氢呋喃 、 氯苯 为溶剂， 反应 1.0h， 生成 [κ2(P,F)-PiPr2(C6H4(2-BF3))Ni(η3-allyl)(acetonitrile-d3)]
  参考文献：
  名称：

  Dimerization of Ethylene by Nickel Phosphino–Borate Complexes

  摘要：

  Trifluoroborate-functionalized phosphine ligands react with a variety of nickel(II) precursors to cleanly yield a number of kappa(2)(P,F)-bound nickel complexes, which were characterized crystallographically. In comparison to related palladium complexes, ancillary ligands in the nickel complexes were observed to be generally more weakly bound, and the trifluoroborate ligands were more easily displaced by coordinating solvents that did not cause a similar displacement in a related palladium system. Such weaker ligand coordination resulted in a much faster dimerization of ethylene. Experiments conducted under constant ethylene pressure saw the suppression of the isomerization of 1-butene observed in related palladium complexes; higher oligomers were also generated under such conditions.

  DOI：

  10.1021/om400288u