[Rh(κ3-NC5H3-2,6-(CH2PMes2)2)(PCy3)][B(C6H3(CF3)2-3,5)4] | 1323954-56-8

• 英文名称: [Rh(κ3-NC5H3-2,6-(CH2PMes2)2)(PCy3)][B(C6H3(CF3)2-3,5)4]
• CAS: 1323954-56-8
• 化学式: C₃₂H₁₂BF₂₄*C₆₁H₈₄NP₃Rh
• 分子量: 1890.39
• InChiKey: OMMXDMSPTHMICY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Rh(κ3-NC5H3-2,6-(CH2PMes2)2)(PCy3)][B(C6H3(CF3)2-3,5)4] 、 乙腈 以 乙腈 为溶剂， 生成 [Rh(κ3-NC5H3-2,6-(CH2PMes2)2)(acetonitrile)][B(C6H3(CF3)2-3,5)4]
  参考文献：
  名称：

  [Rh{NC₅H₃-2,6-(CH₂P^tBu₂)₂}(PCy₃)][BAr^F₄]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound

  摘要：

  An expedient new route to the cationic [(PNPtBu)Rh(L)](+) metal fragments (PNPtBu = K-3-NC5H3-2,6-(CH2P Bu-t(2))(2); L = CO, acetone, ethene, MeCN, N-2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy3)][BAr4F] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNPtBu)Rh(H-2)][BAr4F](center dot)[(PNPR)Rh(PCy3)][BAr4F] (R=Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center.

  DOI：

  10.1021/om2004964
• 作为产物：
  描述：

  [6-[Bis(2,4,6-trimethylphenyl)phosphanylmethyl]pyridin-2-yl]methyl-bis(2,4,6-trimethylphenyl)phosphane 、 [Rh(1,2,4,5,6,8-dimetheno-s-indacene)(PCy3)][B(C6H3(CF3)2-3,5)4] 以 further solvent(s) 为溶剂， 以53%的产率得到[Rh(κ3-NC5H3-2,6-(CH2PMes2)2)(PCy3)][B(C6H3(CF3)2-3,5)4]
  参考文献：
  名称：

  [Rh{NC₅H₃-2,6-(CH₂P^tBu₂)₂}(PCy₃)][BAr^F₄]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound

  摘要：

  An expedient new route to the cationic [(PNPtBu)Rh(L)](+) metal fragments (PNPtBu = K-3-NC5H3-2,6-(CH2P Bu-t(2))(2); L = CO, acetone, ethene, MeCN, N-2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy3)][BAr4F] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNPtBu)Rh(H-2)][BAr4F](center dot)[(PNPR)Rh(PCy3)][BAr4F] (R=Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center.

  DOI：

  10.1021/om2004964