| 190122-24-8

• CAS: 190122-24-8
• 化学式: C₄H₁₂N*C₉H₁₁Cl₄InN₃O₂
• 分子量: 523.983
• InChiKey: QTNBDAAKCCUXIB-JEGVLFTGSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 sodium diethyldithiocarbamate trihydrate 以 甲醇 为溶剂， 以90%的产率得到indium tris(diethyldithiocarbamate)
  参考文献：
  名称：

  Indium(III) complexes with tridentate nitrogen donor ligands. Synthesis, characterization and crystal structure of complexes with pyridine-2,6-bis(acetyloxime) and 2,6-bis(1-phenyliminoethyl)pyridine

  摘要：

  2,6-Bis (acetyloxime)pyridine, 2,6-C5H3N(C2H3NOH)(2) (L-1), reacts with indium(III) chloride in methanol to give the seven-coordinate complex [InCl3(L-1)(MeOH)]. The structurally similar Schiff base ligand 2,6-bis(1-phenyliminoethyl)pyridine (L-2), 2,6-C5H3N(C2H3NC6H5)(2), however, forms a six-coordinate indium(III) complex of the composition [InCl3(L-2)]. The In-N bond distances are longer by 0.03-0.12 Angstrom in the seven-coordinate compound compared with those in the Schiff base complex. The MeOH ligand in [InCl3(L-1)(MeOH)] can be replaced by Cl- or H2O to give the complex anion [InCl4(L-1)](-) and [InCl3(L-1)(OH2)], respectively. The pentagonal-bipyramidal coordination environment of the metal is preserved during these reactions. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00553-0