perfluorodimorpholinopentane | 133333-40-1

• 英文名称: perfluorodimorpholinopentane
• 英文别名: 4-[1,1,2,2,3,3,4,4,5,5-decafluoro-5-(2,2,3,3,5,5,6,6-octafluoromorpholin-4-yl)pentyl]-2,2,3,3,5,5,6,6-octafluoromorpholine
• CAS: 133333-40-1
• 化学式: C₁₃F₂₆N₂O₂
• 分子量: 710.114
• InChiKey: UACVWTAATNJZPL-UHFFFAOYSA-N

物化性质

• 沸点：
  198.0±40.0 °C(Predicted)
• 密度：
  1.94±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.48
• 重原子数：
  43.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.94
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  1,5-dimorpholino-pentane 在 氢氟酸 作用下， 以26%的产率得到perfluorodimorpholinopentane
  参考文献：
  名称：

  On the electrochemical fluorination of derivatives of morpholine and piperidine

  摘要：

  Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.

  DOI：

  10.1016/s0022-1139(00)80306-1