{Fe(CO)3(1-4-η-6-CO2MeC7H7)} | 106095-12-9

• 英文名称: {Fe(CO)3(1-4-η-6-CO2MeC7H7)}
• CAS: 106095-12-9
• 化学式: C₁₂H₁₀FeO₅
• 分子量: 290.055
• InChiKey: PSAAZWHQNNHGKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Fe(CO)3(1-4-η-6-CO2MeC7H7)} 在 potassium hydride 、 溶剂黄146 作用下， 以 四氢呋喃 为溶剂， 以83%的产率得到{Fe(CO)3(1-4-η-5-CO2MeC7H7)}
  参考文献：
  名称：

  Isomerization pathways of (acylcycloheptatriene)iron tricarbonyl complexes

  摘要：

  The (7-exo-acylcycloheptatriene)Fe(CO)3 complexes (7-acyl) prepared by acylation of the mild organometallic nucleophile (eta(3)-C7H7)Fe(CO)3- isomerize readily to their 5-acyl and 6-acyl isomers. The 5-acyl isomer can be prepared in high yield by deprotonation of 7-acyl or 6-acyl followed by a proton quench. Refluxing 5- or 7-acyl in methanol gives the 6-acyl isomer. Rate studies have been carried out on the sequential isomerization of 7-acyl to 5-acyl to 6-acyl. Data were obtained by H-1 NMR monitoring in methanol-d4 at 40-degrees-C. The results indicate that both steps of the isomerization involve an intermolecular proton-exchange mechanism. Solvent deprotonation of any of the three acyl isomers gives a common conjugate base that can be reprotonated at three sites. Kinetic protonation gives 5-acyl, and thermodynamic protonation gives 6-acyl. Mass spectral analysis shows small but significant amounts of multiple deuterium incorporation, suggesting that the common anion intermediate can also be protonated at the metal to give a transient iron hydride.

  DOI：

  10.1021/om00037a058
• 作为产物：
  描述：

  {1-4-η-7-exo-carbomethoxycycloheptatriene}iron tricarbonyl 以 甲醇 为溶剂， 以81%的产率得到{Fe(CO)3(1-4-η-6-CO2MeC7H7)}
  参考文献：
  名称：

  Isomerization pathways of (acylcycloheptatriene)iron tricarbonyl complexes

  摘要：

  The (7-exo-acylcycloheptatriene)Fe(CO)3 complexes (7-acyl) prepared by acylation of the mild organometallic nucleophile (eta(3)-C7H7)Fe(CO)3- isomerize readily to their 5-acyl and 6-acyl isomers. The 5-acyl isomer can be prepared in high yield by deprotonation of 7-acyl or 6-acyl followed by a proton quench. Refluxing 5- or 7-acyl in methanol gives the 6-acyl isomer. Rate studies have been carried out on the sequential isomerization of 7-acyl to 5-acyl to 6-acyl. Data were obtained by H-1 NMR monitoring in methanol-d4 at 40-degrees-C. The results indicate that both steps of the isomerization involve an intermolecular proton-exchange mechanism. Solvent deprotonation of any of the three acyl isomers gives a common conjugate base that can be reprotonated at three sites. Kinetic protonation gives 5-acyl, and thermodynamic protonation gives 6-acyl. Mass spectral analysis shows small but significant amounts of multiple deuterium incorporation, suggesting that the common anion intermediate can also be protonated at the metal to give a transient iron hydride.

  DOI：

  10.1021/om00037a058

文献信息

• Airoldi; Barbera; Deganello, Organometallics, 1987, vol. 6, # 2, p. 398 - 403
  作者：Airoldi、Barbera、Deganello、Gennaro

  DOI：——

  日期：——