fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn-p-toluenesulfonate | 133872-65-8

• 英文名称: fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn-p-toluenesulfonate
• CAS: 133872-65-8
• 化学式: C₃₆H₃₁MnO₆P₂S
• 分子量: 708.59
• InChiKey: SPOLTSAKFZEGEN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn-p-toluenesulfonate 、 sodium ethanolate 以 乙醇 为溶剂， 以81%的产率得到fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn(OC₂H₅)
  参考文献：
  名称：

  Mandal, Santosh K.; Ho, Douglas M.; Orchin, Milton, Inorganic Chemistry, 1991, vol. 30, # 9, p. 2244 - 2248

  摘要：

  DOI：
• 作为产物：
  描述：

  fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I) 、 对甲苯磺酸 以 二氯甲烷 为溶剂， 以93%的产率得到fac-(CO)3(1,2-bis(diphenylphosphino)ethane)Mn-p-toluenesulfonate
  参考文献：
  名称：

  Mandal, Santosh K.; Ho, Douglas M.; Orchin, Milton, Inorganic Chemistry, 1991, vol. 30, # 9, p. 2244 - 2248

  摘要：

  DOI：

文献信息

• The synthesis of alkoxycarbonyl, carbamoyl and isocyanato complexes, fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO]. The single crystal structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO
  作者：Santosh K. Mandal、Douglas M. Ho、Milton Orchin

  DOI：10.1016/s0277-5387(00)83162-9

  日期：1992.1

  The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.
• Reaction of electrophiles with manganese(I) and rhenium(I) alkoxide complexes: reversible absorption of atmospheric carbon dioxide
  作者：Santosh K. Mandal、Douglas M. Ho、Milton Orchin

  DOI：10.1021/om00029a032

  日期：1993.5

  The transition metal alkoxides fac-(CO)3(P-P)MOR [where M is Mn or Re, P-P is either 1,2-bis(diphenylphosphino)ethane (dppe) or 1,3-bis(diphenylphosphino)propane (dppp), and R is either CH3, C2H5, or CF3CH2] react readily at room temperature with CO2, CS2, and PhNCO by insertion of these electrophiles into the metal-oxygen bond. The reactions with C02 leading to the corresponding carbonato complexes fac-(CO)3(P-P)MOC(O)OR are of special interest; benzene solutions of the alkoxides can even absorb CO2 from the atmosphere. All the carbonato complexes release C02 When argon is bubbled through solutions of them, regenerating the alkoxides. These equilibrium reactions make it possible to exchange the C02 of the carbonato complexes by treatment of them with CS2 or PhNCO. Only the C02 reaction is reversible under mild conditions. When a solution of fac-(CO)3(dppe)MnOC(O)OCH3 is treated with CH3NH2 followed by CO2 the metallourethane complex (CO)3(dppe)MnOC(O)NHCH3 is formed. The X-ray crystal structure of fac-(CO)3(dppe)MnOC(O)OCH3 is presented.