| 1076232-20-6

• CAS: 1076232-20-6
• 化学式: C₁₇H₂₅ClMnN₅*ClO₄
• 分子量: 489.261
• InChiKey: CNZSOSDINOTKRK-JWRHQXMQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,4-双(3-氨基丙基)哌嗪 、 吡啶-2,6-二甲醛 、 manganese(II) perchlorate hexahydrate 以 甲醇 、 乙醇 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  Synthesis and crystal structure of Mn(II) complexes with novel macrocyclic Schiff-base ligands containing piperazine moiety

  摘要：

  A series of Mn(II) macrocyclic Schiff-base complexes [MnL(n)Cl](+) (n = 1-4) have been prepared via the Mn(II) templated [1+1] cyclocondensation of 2,6-diacetylpyridine or 2,6-pyridinedicarbaldehyde with the symmetrical 1,4-bis(3-aminopropyl)piperazine or the novel asymmetrical N,N'(2-aminoethyl)(3-aminopropyl)piperazine linear amines containing piperazine moiety. The complexes have been characterized by elemental analyses, IR, FAB-MS, magnetic studies and conductivity measurements. The crystal structure of [MnL(2)(CH(3)OH)CI](ClO(4)) and [MnL(4)Cl](PF(6)) complexes have also been determined showing the metal ion in a N(4)OCl pentagonal bipyramidal or N(4)Cl highly distorted octahedral geometry, respectively. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.07.012