Fe(1,2-ethanedithiolate)(CO)2(dppe) | 1021149-24-5

• 英文名称: Fe(1,2-ethanedithiolate)(CO)2(dppe)
• 英文别名: Fe(S(CH2)2S)(CO)2(dppv)；Fe(S(CH2)2S)(CO)2(cis-1,2-bis(diphenylphosphino)ethylene)
• CAS: 1021149-24-5
• 化学式: C₃₀H₂₈FeO₂P₂S₂
• 分子量: 602.478
• InChiKey: IBILEKNFVWKSAT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Fe(1,2-ethanedithiolate)(CO)2(dppe) 、 [(acenaphthene)Mn(CO)₃]BF₄ 以 二氯甲烷 为溶剂， 反应 20.0h， 以90%的产率得到[(CO)₃Mn(pdt)Fe(CO)₂(dppe)]BF₄
  参考文献：
  名称：

  羰基二硫醇亚铁作为 FeFe、FeCo 和 FeMn 羰基二硫醇盐的前体

  摘要：

  报道了式 Fe(dithiolate)(CO) 2 (diphos) 的配合物及其用于制备均和异双金属二硫醇衍生物的用途。起始二硫醇铁是通过 FeCl 2和 CO 与螯合二膦和二硫醇的一锅反应制备的，其中二硫醇= S 2 (CH 2 ) 2 2– (edt 2– ), S 2 (CH 2 ) 3 2– (pdt 2– ), S 2 (CH 2 ) 2 (C(CH 3 ) 2 ) 2– (Me 2 pdt 2–) 和 diphos = cis -C 2 H 2 (PPh 2 ) 2 (dppv), C 2 H 4 (PPh 2 ) 2 (dppe), C 6 H 4 (PPh 2 ) 2 (dppbz), C 2 H 4 [ P(C 6 H 11 ) 2 ] 2 (dcpe)。将57 Fe 掺入这种结构单元复合物始于将57 Fe 转化为57 Fe 2 I 4 (i PrOH) 4，然后用K 2

  DOI：

  10.1021/om400752a
• 作为产物：
  描述：

  一氧化碳 、 1,2-Ethanedithiol, disodium salt 、 1,2-双(二苯基膦)乙烷 、 iron(II) chloride 以 四氢呋喃 为溶剂， 生成 Fe(1,2-ethanedithiolate)(CO)2(dppe)
  参考文献：
  名称：

  X-ray photochemistry in iron complexes from Fe(0) to Fe(IV) – Can a bug become a feature?

  摘要：

  Under intense soft X-ray irradiation, we have observed time-dependent changes in the soft X-ray spectra of virtually all the Fe coordination complexes that we have examined, indicating chemical transformation of the compound under study. Each compound, with oxidation states ranging from Fe(IV) to Fe(0), has been studied with either Fe L-edge spectroscopy or N K-edge spectroscopy. We find that very often a well-defined spectroscopic change occurs, at least initially, which is apparently capable of straightforward interpretation in terms of X-ray induced photoreduction, photooxidation or ligand photolysis. We briefly discuss the probable chemical nature of the changes and then estimate the rate of chemical change, thereby establishing the necessary radiation dose. We also demonstrate that the photochemistry not only depends on the Fe oxidation state but also the coordination chemistry of the complex. It seems that a proper understanding of such X-ray photochemical effects could well greatly assist the assignment of soft X-ray spectra of uncharacterized metal sites. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.10.039