| 137696-27-6

• 分子结构分类: 无机化合物 - 均相金属化合物
• CAS: 137696-27-6
• 化学式: AlH₆N₂
• 分子量: 61.0426
• InChiKey: OMKGULHSQWLBMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.06
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  氨 、 氢化铝 以 gaseous matrix 为溶剂， 生成 aluminum-ammonia complex 、 aluminum-ammonia complex 、 aluminum-ammonia complex 、 、 aluminum-ammonia complex
  参考文献：
  名称：

  Pulsed laser reactive ablation of Al in an ammonia atmosphere: photoionization thresholds and structures of Al–NH3 clusters

  摘要：

  A photoionization study of the aluminum ammonia clusters produced by the interaction of the laser ablated aluminum vapour with gaseous NH3 is reported. In the near-threshold photoionization spectrum of Al(NH3) the observed structures are assigned to vibrational frequencies of the ionized cluster. Ionization potentials of Al(NH3)(n) clusters with 2 less than or equal to n less than or equal to 13 have been measured. The cluster ionization potentials are shifted to lower energies compared with the hare Al atom and they decrease almost monotonically with increasing cluster size. This is consistent with a model in which the metal valence electron is delocalized in a Rydberg-like surface state. For small clusters the difference between the binding energy of the ion and the neutral complexes is compared with energetics calculated by a density functional method. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s0009-2614(97)01406-1