Benzylphenylaminyloxid (Radikal) | 34295-25-5

• 英文名称: Benzylphenylaminyloxid (Radikal)
• 英文别名: Phenyl-benzyl-aminoxyl
• CAS: 34295-25-5
• 化学式: C₁₃H₁₂NO
• 分子量: 198.244
• InChiKey: JHMZNKAQZSZPJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  苯甲基苯胺 在 间氯过氧苯甲酸 作用下， 以 苯 为溶剂， 生成 Benzylphenylaminyloxid (Radikal)
  参考文献：
  名称：

  Radical transformations of some N-alkylanilines by their oxidation with different agents: an EPR study

  摘要：

  N-Alkylanilines X-NH-Ph (Ph = substituted phenyl ring) with two different types of alkyl substituent X [X = C2H5-CO-CH2CH(Ph), X = CH3, C2H5, CH(CH3)(2), CH2C6H5] were oxidized using different agents. While oxidation with 3-chloroperbenzoic acid leads to production of the corresponding aminoxyl radicals X-NOaEuro cent-Ph, it was confirmed that application of PbO2 resulted in the formation of aminyl radicals X-N-aEuro cent-Ph, as indirectly proved by the spin-trapping method. Contrary to those transformations, with employment of either Pb(OAc)(4) or t-BuO (2) (aEuro cent) radical, reactions taking place on the alkyl substituent were also observed.

  DOI：

  10.1007/s00706-012-0874-6

文献信息

• Cholvad, Vlado; Stasko, Andrej; Tkac, Alexander, Collection of Czechoslovak Chemical Communications, 1981, vol. 46, # 4, p. 823 - 832
  作者：Cholvad, Vlado、Stasko, Andrej、Tkac, Alexander、Buchanenko, Anatolii L.、Malik, Lubomir

  DOI：——

  日期：——