2-[2-oxo-2-(p-methoxyphenyl)]ethyliden-3,3,3,7,7,7-hexacarbonyl-1-oxo-3,7-diferra-1,4-dithiatricycle[2.2.1.1(3,4)]heptane | 688025-42-5

• 英文名称: 2-[2-oxo-2-(p-methoxyphenyl)]ethyliden-3,3,3,7,7,7-hexacarbonyl-1-oxo-3,7-diferra-1,4-dithiatricycle[2.2.1.1(3,4)]heptane
• CAS: 688025-42-5
• 化学式: C₁₈H₁₂Fe₂O₉S₂
• 分子量: 548.114
• InChiKey: KGCRQNOUMGZGEI-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 1-(1-oxo-1,3-dithiolan-2-yliden)-p-methoxyacetophenone 以 四氢呋喃 为溶剂， 以15%的产率得到2-[2-oxo-2-(p-methoxyphenyl)]ethyliden-3,3,3,7,7,7-hexacarbonyl-1-oxo-3,7-diferra-1,4-dithiatricycle[2.2.1.1(3,4)]heptane
  参考文献：
  名称：

  Novel dinuclear iron(0) complexes from α,β-unsaturated ketones β-positioned with sulfide and sulfoxide groups

  摘要：

  The reaction of Fe-2(CO)(9) with alpha,beta-unsaturated ketones analogues containing beta-positioned sulfoxide group 2a-2d afforded di-nuclear Fe(0) complexes 3a-3d and 5 which were characterized by IR, mass spectrometry, H-1 and C-13 NMR spectroscopy, the structures of 3a, 3c and 5 were established by X-ray diffraction analysis. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.12.015