[1-(6-benzo[b]thiophen-2-yl-pyridin-2-yl)-ethylidene]-(2,6-diisopropyl-phenyl)-amine cobalt(II) dichloride | 415928-04-0

• 英文名称: [1-(6-benzo[b]thiophen-2-yl-pyridin-2-yl)-ethylidene]-(2,6-diisopropyl-phenyl)-amine cobalt(II) dichloride
• CAS: 415928-04-0；706820-04-4
• 化学式: C₂₇H₂₈Cl₂CoN₂S
• 分子量: 542.498
• InChiKey: IJNHLAOQYKACJM-CTSCVECRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(II) chloride 、 [1-(6-benzo[b]thiophen-2-yl-pyridin-2-yl)-ethylidene]-(2,6-diisopropyl-phenyl)-amine 以 四氢呋喃 为溶剂， 以71%的产率得到[1-(6-benzo[b]thiophen-2-yl-pyridin-2-yl)-ethylidene]-(2,6-diisopropyl-phenyl)-amine cobalt(II) dichloride
  参考文献：
  名称：

  Oligomerisation of ethylene to linear α-olefins by tetrahedral cobalt(II) precursors stabilised by benzo[b]thiophen-2-yl-substituted (imino)pyridine ligands

  摘要：

  On activation by MAO, 2-(imino)pyridine cobalt dichlorides bearing a benzo[b]thiophen-2-yl substituent in the 6-position of the pyridine ring oligomerise ethylene to alpha-olefins with turn-over-frequencies as high as 1.5 x 10(6) mol of C2H4 converted (mol of Co x h)(-1) and productivities as high as 3769 kg of oligomers (mol of Co x h x bar)(-1). Aldimine precursors are more active than ketimine analogues, yet ketimines give higher molecular weight oligomers. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.10.034